DataTitoloAbstract
08/05/2007 0.00.00 STAPELIA: LAMPIONE FOTOVOLTAICO/COMPONENTE MULTIFUNZIONALE PER L’INSERIMENTO IN CONTESTI SENSIBILI (ELEMENTO ISOLATO LUMINOSO CON FUNZIONAMENTO IN MODALITÀ STAND-ALONE/GRID CONNCTED) La diffusione dei sistemi fotovoltaici integrati in architettura non può prescindere dal soddisfacimento dei requisiti estetici che ne determinano la “accettabilità” da parte dei progettisti, dei committenti e degli utenti; pertanto particolare rilievo assume la messa a punto di componenti fotovoltaici multifunzionali sviluppati tenendo conto del “punto di vista dell’architetto”, che guarda ad essi come occasioni progettuali alla stregua degli altri elementi del processo di design, se esso viene utilizzato integrato nell’involucro edilizio, così come nel paesaggio. L’invenzione in oggetto concerne un componente fotovoltaico luminoso multifunzionale pensato per l’integrazione in siti “sensibili”, vale a dire pregevoli da un punto di vista ambientale o anche storico-archeoogico. In particolare si tratta di un lampione fotovoltaico, concepito traendo spunto dalle forme di un fiore denominato “Stapelia”, come verrà meglio chiarito in seguito. L’obiettivo è quello di mitigare l’impatto visivo che l’inserimento di un sistema fotovoltaico produce in un contesto sensibile, migliorandone notevolmente la valenza formale. Pubblicazioni/2007/BrevettoStapelia.pdf1340KB
02/04/2007 0.00.00 Micromorph tandem solar cells: influence of microcrystalline silicon bottom cell on device performance Micromorph tandem solar cells have been fabricated growing the intrinsic layers of both components by VHF-PECVD at 100 MHz at low substrate temperature (150 °C). The influence of the microcrystalline p-layer on the bottom cell has been studied by growing single microcrystalline devices. Different growth regimes have been explored for the bottom cell by changing both chamber pressure and plasma power. The effect of the structural composition of the microcrystalline absorber layer on the electrical parameters of the device has been investigated. High short circuit current density and an almost constant FF in a wide silane concentration range are obtained when using large power to pressure ratio (0.5 W/Pa). However low open circuit voltage is generally found in this regime. The largest VOC values are found at 67 Pa and power to pressure ratio of 0.3 W/Pa, where the highest efficiency (11.1%) is reached. Keywords: Tandem, Micro Crystalline Si, Thin Film. Pubblicazioni/2007/Micromorph_tandem_solar_cells.pdf P. Delli Veneri, L. V. Mercaldo, P. Aliberti, P. Ciani, I. Usatii, C. Privato Enea - Portici Research Center Località Granatello - 80055 Portici (Napoli) – Italy Tel: +39-0817723259, fax +39-0817723344, e-mail: paola.delliveneri@portici.enea.it 554Kb
02/04/2007 0.00.00 A YEARLY ENERGY PRODUCTION OF 10KWP DOUBLE AXIS PV SYSTEM FEEDING AN ELECTROLYSER FOR THE HYDROGEN PRODUCTION Within the operating program aimed to on-site power generation, launched by Regione Campania for the years 2000/2006, ENEA (Italian National Agency for New Technologies, the Energy and the Environment) planned the installation of a double axis Photovoltaic Plant feeding an electrolyser for the hydrogen production. The facility, which is located in the Research Centre of Portici near to Naples, has been monitored during its operating first year. The PV generator is realized by 4 standard units of 2.4kWp each for a total power of 9.6kWp at STC. The PV array includes 12 modules Sanyo Heterojunction with Intrinsic Thin layer HIP-200NHE1 mounted on the double axis sun Deger Tracker 1600EL. The 10kW alkaline electrolyser for hydrogen production, operating at atmospheric pressure, has been used. The focus of this work is to illustrate the energetic performance of PV plant after one working year. As regard a comparative analysis among PV installations of different type - flat system, tilted single axis tracking system, double axis tracking system - has been performed. Moreover a detailed economical analysis in order to emphasize the economical and energetic advantages due to the use of the double axis tracking PV technology has been developed. Keywords: double axis PV system, energetic performance, technical and economical analysis. A_YEARLY_ENERGY_PRODUCTION_DOUBLE_AXIS_PV_SYSTEM.pdf G. Graditi, C. Cancro, A. Merola, C. Privato Centro Ricerche ENEA - Agenzia nazionale per le nuove tecnologie, l’energia e lo sviluppo economico sostenibile. Via Vecchio Macello - 80055 Portici (Napoli) - Italy tel:+390817723400; fax:+390817723344 mail to: giorgio.graditi@portici.enea.it 77Kb
02/04/2007 0.00.00 A PROCEDURE TO EVALUATE THE ENERGY PRODUCTION AND THE INCIDENCE OF THE THERMAL LOSSES FOR A C-MODULE MOCK-UP The comparison of the different loss factors of a C-module provides indications to optimize the design of the component in terms of geometrical concentration and passive cooling, with the aim of minimize the cost for the produced energy unit. In this work a detailed energy losses analysis of different C-module mock-ups have been performed and the thermal losses incidence have been evaluated. The results show that, from statistical point of view, the weight of the so named “circumsolar radiation” should not be neglected in order to: estimate the yearly energy production, evaluate experimentally the efficiency of a PV C-module, select the right installation site from the environmental specifications point of view. The simplicity and flexibility of the proposed approach allow its application in a large number of cases to help the design of a effective C-system. Keywords: C-module energy performance, thermal losses, circumsolar radiation. Pubblicazioni/2007/PROCEDURE_TO_ EVALUATE_ENERGY_PRODUCTION_ AND_ INCIDENCE.pdf G. Contento(1), G. Graditi(2), F. Roca(2) (1)ENEA Centro Ricerche, S.S. 7 Appia, km 713.700 - 72100 Brindisi, Italy tel: +390831201430; fax: +390831201431; email: gaetano.contento@brindisi.enea.it (2)ENEA Centro Ricerche, Località Granatello - 80055 Portici (NA), Italy tel: +390817723400; fax: +390817723344 368Kb
02/04/2007 0.00.00 IMPROVEMENTS IN THE PHOCUS C-MODULE OPTICAL DEVICES The aim of this paper is the analysis of the influence of the different technological solutions developed for the optical devices on the PhoCUS C-module energetic performance. Two concentration stages have been used: the first one is a refractive optical lens and the second one is a reflective Secondary Optical Elements (S.O.E.). In particular two types of primary optics have been developed: the Prismatic and the Hybrid lens. The Prismatic lens is made of an array of square refractive prisms of size 7,8x7,8 mm2 in the central portion, and 3,9x3,9 mm2 in the peripheral areas. The hybrid lens is made of prismatic refractive prisms in the central portion, and Fresnel grooves in the peripheral region. The comparison of the behaviour of these devices in different working conditions has been carried out; the results show that the optical efficiencies of prismatic and hybrid lens are very closely. The S.O.E. has the shape of a truncated inverted pyramid with one tilt angle; it is realized by a plastic case with a metallic inner surface used as a reflector. The influence of two different types of aluminium sheet (unpolished or polished), used as reflective materials, has been investigated by means many indoor and outdoor tests. The results shown an increase of the optical efficiency, for the polished aluminium, about of 3%. Finally several tests in order to define the optical acceptance of the C-module have been performed: the result show that the use of the S.O.E. allows an acceptance angle about of ±0,6°. Keywords: Concentrators; Optical Losses; Hybrid lens Pubblicazioni/2007/IMPROVEMENTS_IN_PHOCUS_C_MODULE_OPTICAL_DEVICES.pdf C. Cancro1, G. Graditi, A. Romano, R. Fucci (1)ENEA R. C. Portici, Agenzia nazionale per le nuove tecnologie, l’energia e lo sviluppo economico sostenibile via Vecchio Macello, località Granatello, 80055 Portici (NA), Italia mail to: carmine.cancro@portici.enea.it phone +39 081 7723278 fax +39 081 7723344 164Kb
02/04/2007 0.00.00 OPTIMIZATION OF THE CONTACTING STRUCTURE OF HIGH EFFICIENCY C-SI SOLAR CELLS FOR CONCENTRATING SYSTEMS In the present work we have investigated the influence of metal grid and assembly on the cell performance at one sun and under concentrated light. A conventional solar cell structure has been used and a number of devices with metal grids having similar shadowing but different width and spacing between fingers have been realised. The finger width was restricted to the lower values technologically feasible considering the future industrialisation of this process, namely transferring the concentration solar cell technology from lab-scale to prepilot level. The very high current level of this kind of devices imposed the use of thick fingers/busbar on the contacting structure in order to reduce the ohmic losses. We made a comparative study of the electrical behaviour of different devices (current-voltage and quantum efficiency characterization) at one sun and under concentrated light, before and after assembling, to investigate the influence of different metal grid on the electrical performances of the devices. The best cell realized in our laboratory achieved the efficiency of more than 20% at 1 sun, 21% at 100 suns and more than 19% at 180 suns. Keywords: c-Si, Concentrator Cells, High Efficiency. Pubblicazioni/2007/OPTIMIZATION_CONTACTING_STRUCTURE_HIGH_EFFICIENCY_C-SI_SOLAR_CELLS.pdf P. Morvillo*, E. Bobeico, G. Flaminio, F. Formisano, R. Fucci, F. Roca C.R. ENEA Portici Loc. Granatello, I-80055 Portici (Napoli), Italy *Email: Morvillo@portici.enea.it 148Kb
02/04/2007 0.00.00 OPTIMIZATION OF THE LIGHTING PHOTOVOLTAIC COMPONENT STAPELIA In Summer 2006 five prototypes of a PV lighting component called Stapelia have been realized and installed in the garden of the ENEA (Italian National Agency for New Technologies, the Energy and the Environment) Research Centre in Portici. Stapelia is fit to the integration in valuable sites; its shape, and consequently its name, have been inspired by the structure of the homonymous tropical flower. The geometry is based on a pentagon, and the basic idea is that one or more elements (flowers) can be “planted” where an electrical supply or a places improvement are required. A good design would be the most important feature of this PV component, ensuring a good matching with the context (landscape or valuable places), and also a satisfying balance between the different functions the component has. Stapelia has been patented as utility model, industrial design, registered community trade mark, and an Italian company has been granted a commerce and production license. At the moment an optimization process is involving different Enea units, focusing on the single aspects that have been integrated into the design of Stapelia and monitoring the real performance of the component (lighting, photovoltaic energy generation). A comparative analysis of the best solutions (among the investigated ones), ensuring a good balance between the energetic and lighting performance, and the costs is in progress All the solutions are analyzed in order to preserve the “aesthetic” value of the component. Keywords: building integration, PV lighting component, diffusion Pubblicazioni/2007/OPTIMIZATION_LIGHTING_PHOTOVOLTAIC_COMPONENT_STAPELIA.pdf A. Scognamiglio*, C. Cancro*, F. Formisano*, C. Privato* and S. Fumagalli**, G. Leonardi** *ENEA Portici Research Centre, località Granatello, 80055 Portici (NA), Italy **ENEA Ispra Research Centre, via Fermi 2749 TP144, 21020 Ispra (VA), Italy mail to: alessandra.scognamiglio@portici.enea.it; phone +39 081 7723304 fax +39 081 7723344 349Kb
02/04/2007 0.00.00 MULTI-SOURCE PULSED REFLECTOMETER FOR FAST OPTICAL MAPPING OF A PV MODULE An innovative, non destructive, method and the relative apparatus for the optical mapping of large photovoltaic surfaces, i.e. photovoltaic modules and large optical windows, is described. The method has been applied by the following procedure: illuminating a portion of the test surface by a collimated and pulsed beam, incident on the surface at a variable angle between 0° e 70°; measuring the total or diffuse hemispherical reflectance; translating the sample on the x-y plane; building a map of optical reflectance of the test surface for each angle of incidence. The method is particularly useful for the analysis of the optical properties of crystalline Silicon modules and for the analysis of the optical and electrical properties of integrated thin films modules (a-Si, CIS), when photocurrent measurements are made simultaneously to the optical measurements. Keywords: Reflectometer, Optical Losses, PV Module Pubblicazioni/2007/MULTI-SOURCE_PULSED_REFLECTOMETER_ FOR_ FAST_OPTICAL_MAPPING.pdf A. Parretta*1,2, G. Nenna3, G. Flaminio3, R. Schioppo4, A. Aldrin5 1ENEA Centro Ricerche “E. Clementel”, Via Martiri di Monte Sole 4, 40129 Bologna (BO), Italy. 2Physics Department, University of Ferrara, Via Saragat 1, 44100 Ferrara (FE), Italy. 3ENEA Centro Ricerche Portici, Località Granatello,80055 Portici (NA), Italy. 4ENEA Area Sperimentale M.te Aquilone, S.S. Garganica 89, 71043 Manfredonia (FG), Italy. 5Universitat de Barcelona, Departament de Física Aplicada i Òptica Martí i Franquès, 1-11, 5ª Planta, 08028-Barcelona, Spain *Phone: +39 (0)51 6098617; Fax: +39 (0)51 6098767; E-mail: antonio.parretta@bologna.enea.it 370Kb
02/04/2007 0.00.00 FIELD TESTING OF THE PhoCUS SOLAR TRACKER BY MEANS OF A NOVEL OPTOELECTRONIC DEVICE The focus of the paper is to evaluate the solar tracker accuracy, installed in R.C. ENEA in Portici (NA) within the PhoCUS (Photovoltaic Concentrators to Utility Scale) project, using a novel optoelectronic device (OED) designed and patented by ENEA [1]. In this work a detailed analysis of the misalignments causes, considering the influence of the different factors (mechanical and thermal deformations, set-up errors, inefficiency of feedback, etc.), has been performed by the authors. On the basis of the experimental data, collected in absence of feedback, an accurate improvement of the feedback algorithm has been obtained. After, several outdoor tests in presence of feedback sensor have been carried out. The results have been shown an high increase of the tracking accuracy. Pubblicazioni/2007/Madrid_ENEA_Field testing.pdf C. Cancro, G. Graditi, G. Leanza, F. Pascarella, A. Sarno and D. Mancini* Center Research ENEA (Agenzia nazionale per le nuove tecnologie, l’energia e lo sviluppo economico sostenibile) Via Vecchio Macello 80055 Portici (NA), Italy - Tel: +3908177232111; Telefax: +390817723344 *Atec Robotics, via G. Nicotera 10, 80132 Napoli - Tel: +390814421546; Telefax: +390812110228 Corresponding author: carmine.cancro@portici.enea.it 639KB
02/04/2007 0.00.00 DEVELOPMENT AND PERFORMANCE ANALYSIS OF THE PHOCUS C-MODULE Relevance is given in the ENEA PhoCUS project for the development of a new technology able to realize a monolytic low-cost photovoltaic module suitable to work under medium concentration (200X). Several technical problems were faced and overcome about the development of the solar cells, the system housing integrating optics and receivers, the realization of the lenses and heat spreaders and the mechanical-thermal and electrical performance modelling. In order to meet the low cost requirement a large use of conventional materials and components together with manufacturing and assembling techniques addressed to a cheap full automation have been adopted in cooperation with national industrial operators. The efforts made brought to file many patents relating the novel solutions, as for the C-module, the optics. A final product meeting requested requirements was obtained. The paper will report about the indooroutdoor characterization and the detailed performance analysis with also comparison to expected values. Pubblicazioni/2007/Madrid_ENEA_Phocus Module.pdf F. Roca*, C. Cancro, R. Fucci, G. Flaminio, G. Graditi, G.Leanza, C. Privato, A. Romano, A. Sarno, ENEA Portici Research Center Via Vecchio Macello 80055 Portici (NA), Italy Tel: +390817723270; Telefax: +390817723344 *Corresponding author: roca@portici.enea.it 335KB
02/04/2007 0.00.00 ENEA’S EXPERIENCE ON THE PV-CONCENTRATORS TECHNOLOGY: THE PHOCUS PROJECT The PhoCUS (Photovoltaic Concentrators to Utility Scale) project was outlined in order to develop a low-cost photovoltaic concentrators (PV-C) technology, based on the point focus approach, to be applied in Mediterranean climates, like Southern Italy. The first phase of the project was over: the technology for each device and component was developed, the prototypes were realized and the first demonstrative and experimental systems were installed becoming operative. The experimental results coming from field testing are proving the effectiveness, in terms of operating efficiency and reliability, of the adopted technological options. The characterization of the single components together with the understanding of the initial failures has allowed to identify the critical points and to apply some modifications in terms of hardware and of assembling procedure. The production cost of the main components (module and heliostat) are strongly dependent on the size. Economical analysis has shown that the cost reduction expected for a mass production is not enough to make PV-C technology competitive: the key factors for the success are higher efficiency solar cell together with higher concentration ratio and scale economy. Anyway, it is important to get a reliability level comparable with the flat plate PV in terms of life time. The paper will report the Enea’s experience acquired and on the basis of a sensitivity economic analysis and the second phase of the PhoCUS project will be outlined. Pubblicazioni/2007/Madrid_EneaPhocusGeneral.pdf Angelo Sarno*, Felice Apicella, Michele Pellegrino, Carlo Privato, Francesco Roca Enea Portici Research Center Loc.Granatello 80055 Portici (Napoli) - Italy – (*) Corresponding author: sarno@portici.enea.it Tel: +390817723202;Fax: +390817723344 379KB
25/05/2006 0.00.00 ZNO protetto protetto Pubblicazioni/2006/ZnO 3DV.3.33.pdf protetto 565KB
24/05/2006 0.00.00 A LANDSCAPE INTEGRATED PHOTOVOLTAIC COMPONENT CALLED “STAPELIA” An important subject to investigate in the field of the diffusion of photovoltaic systems is the development of landscape integrated PV components fit to the installation in valuable sites, that are characterized by an high cultural value (such as archaeological areas, natural parks, small islands). The aesthetic value of the components is the most important feature to ensure a good matching with the context (landscape or valuable places), that means the acceptability of the energy solar generators. This work is focused on the design of a photovoltaic lighting component fit to the integration in valuable sites, “Stapelia”, which shape, and consequently name, have been inspired by the structure of the homonymous tropical flower. The geometry is based on a pentagon, and the basic idea is that one or more elements (flowers) can be “planted” where an electrical supply or a places improvement are required. Five prototypes of Stapelia have been realized and installed in the garden of the ENEA (Italian National Agency for New Technologies, the Energy and the Environment) Research Centre in Portici, that is located within the area of the Vesuvio National Park, on the sea front. Keywords: building integration, diffusion, PV lighting component Pubblicazioni/2006/Stapelia 6DV 4 11.pdf A. Scognamiglio, C. Cancro. F. Formisano, G. Graditi, C. Privato mail to: alessandra.scognamiglio@portici.enea.it; phone +39 081 7723304 fax +39 081 7723344 ENEA R.C. Portici, località Granatello, 80055 Portici (NA), Italy 297KB
23/05/2006 0.00.00 COMPARISON BETWEEN TWO DIFFERENT S.O.E. GEOMETRICAL SHAPES TO INCREASE THE PhoCUS C-MODULE ENERGY PERFORMANCES The focus of this work is to present the energetic performance of a Concentration module (C-module) using different configurations of Secondary Optical Element (S.O.E.). The use of S.O.E. can give the following technical advantages: the level of precision of the solar tracker may be lower, the plastic is protected from dangerous outside fire, intrinsic losses in case of non-optimal tracking are reduced, the energy flux over the cell is quite uniform and global costs of the systems are limited. Two S.O.E. which differ in terms of shape have been considered. The first has the shape of a truncated inverted pyramid with one tilt angle; the second has the shape of a truncated overturned pyramid with tree different tilt angles. The solar cell is doweled under the pyramid’s bottom squared hole having the same size of the solar cell. The S.O.E. reflective inner surface has been made of aluminium covered by a reflecting polymeric film (3M Radiant Mirror Film). The experimental tests and numerical simulations have been carried out considering a PV C-system which includes the following elements: prismatic lens, SOE and solar cell. The tests have been performed considering a misalignments range of 0÷1,2° for the solar beam radiation respect to prismatic lens. By means of the software TracePro Expert raytracing simulations have been carried out in order to evaluate the optical efficiency of the lens-secondary system and the non-uniformity of the light flux on the target where the cell is located. Many indoor tests to characterize the S.O.E. optical efficiency in misalignment conditions have been carried out. The PV C-system is assembled in rugged Mock up and fixed on a rotation stage on the optical bench with the solar cell in its focus. It can rotate on its own axis causing a misalignment between the lens and the solar beam direction. Besides, by means of an other experimental Mock-up, motorized by a very accurate tracking system, the S.O.E. efficiency has been measured outdoor. The measured optical efficiencies for the above mentioned S.O.E. configurations have been compared in order to select the best solution and consequently to increase the Cmodule energy performance. Keywords: C-module, secondary optical element, energetic performance, technological features. Pubblicazioni/2006/SOE 5AV.3.16.pdf C. Cancro(1), R. Fucci(1), G. Graditi(1), A. Romano(1), A. Antonini(2), M. Armani(2) (1)ENEA R.C. Portici, località Granatello, 80055 Portici (NA), Italy (2)Dipartimento di Fisica Università di Ferrara, Via Paradiso 12, 44100 Ferrara, Italy mail to: carmine.cancro@portici.enea.it; phone +39 081 7723111 fax +39 081 7723344 243KB
22/05/2006 0.00.00 THERMAL CONTROLLED FLASH TIME ADJUSTABLE SOLAR SIMULATOR FOR CONCENTRATING PV CELLS Concentrating Photovoltaic technology has been requiring new attention after many stops and goes attempts for the past. Due to the importance of the efficiency of the cell for its impact on the economical aspects and technical feasibility of the technology, it is vital to measure in an easily and reliable way the cell electrical characteristics. Unfortunately at the moment there are not many solar simulators specifically designed to perform the IV under illumination characteristic for concentrating cells of certain dimensions, let aside some commercial equipments for small size cells or not marketable built-in devices or various adjustments of solar simulators for flat panels. So in order to fill this critical gap, a project aimed to design a solar simulator for characterising concentrating photovoltaic cells of different sizes and for different suns was devised. The paper intends to describe the equipment and to give a report of an experimental campaign. Keywords: Concentrator cells, characterization Pubblicazioni/2006/Simulatore 5AV.3.14.pdf M. Pellegrino, C. Cancro, G. Flaminio, M. Marciano, C. Privato, F. Roca, A. Romano and A. Sarno ENEA Centro Ricerche Portici Località Granatello. P.O. Box 32, I-80055 Portici (NA), Italy. tel:+39-81-7723-267, Fax:+39-81-7723-344 157KB
21/05/2006 0.00.00 OPTIMIZATION PROCEDURES OF CONCENTRATOR PHOTOVOLTAIC MODULES BASED ON ENERGY COST AND REALISTIC REPORTING CONDITIONS The use of concentrator solar cells in photovoltaic plants significantly reduces the number and area of expensive cells and contributes to reduce the total system cost; photovoltaic concentrator (PV-C) modules optimization involves heat transfer analysis, system performance modelling, cost estimation, material selection applies to lenses, solar cells, heat spreaders, heat sinks, etc. The aim of this work is the development of the cell assembly for the PhoCUS project; this optimization process is based on energy cost. Some calculation methodologies are proposed, which allow to determine the main characteristics of a PV-C module, starting from some experimental measurements of appropriate mock-up in real working conditions. It has been developed and used an empirical model, based on this information, to obtain an optimum combination of the different structures (optimization based on energy cost) for a particular geographical site (Real Reporting Conditions). Keywords: Concentrator, Modelling, Simulation Pubblicazioni/2006/Modules 5AV.3.20.pdf R. Fucci, G. Flaminio, G. Leanza, A. Romano, F. Roca ENEA Research Center Portici – Località Granatello 80055 – Naples – Italy email:fucci@portici.enea.it 157KB
20/05/2006 0.00.00 THERMAL MODELLING OF THE BASIC UNIT OF A C-MODULE The analysis of the thermal performance of a PV concentrator system (PV-C system) is necessary to estimate the energetic yearly production. Moreover, an important goal for the designer is to select the optimal configuration of the basic unit of the C-module (PV Concentrator module) in order to minimize the cost of kWh. In this work a calculation procedure developed by the authors is described: it allows to obtain a suitable thermal model for each configuration of the basic unit of a C-module. The model takes into account the radiative heat transfer and power geometric concentration too. Regarding cooling by natural convenction, instead, it uses a simple yet accurate analytically-based correlation suitably modified and extended by the authors to adapt it to photovoltaic applications. The model has been tested for the C-module basic unit of the PhoCUS (Photovoltaic Concentrator to Utility Scale) project performed by ENEA in Portici Research Centre. The results have been compared with those obtained by means of the Computational Fluid Dynamics (CFD) software such as the Fluent. The model well fits the results obtained by the Fluent with the advantage of a greater flexibility and speed in the resolution of the problem. Keywords: Thermal Performance, Modelling, PV Concentrator Module Pubblicazioni/2006/Modelling 5AV.3.19.pdf (1)ENEA R.C Brindisi, SS 7 km 714, 72100 Brindisi, Italy (2)ENEA R.C. Portici, località Granatello, 80055 Portici (NA), Italy (3)DETEC Naples University Federico II, piazzale Tecchio, 80125 Napoli, Italy mail to: gaetano.contento@brindisi.enea.it; phone: +39 0831 201430; fax: +39 0831 201431 214KB
19/05/2006 0.00.00 DEPOSITION PRESSURE EFFECTS ON THE PERFORMANCE OF MICROMORPH TANDEM SOLAR CELLS GROWN BY VHF-PECVD “Micromorph” tandem solar cells consisting of an amorphous silicon top cell and a microcrystalline silicon bottom cell represent an elegant way of overcoming the efficiency limits of single-junction solar cells and reducing the light induced degradation of amorphous silicon films. These devices allow a good utilization of the solar spectrum due to the bandgap values of the two materials. In this work micromorph tandem solar cells have been realized on Asahi U-type TCO-covered glass substrates. The intrinsic layer of both the amorphous top cell and the microcrystalline bottom cell are grown by VHF-PECVD at 100MHz at low substrate temperature (150 °C). For the bottom cell, low pressure-low power and high pressure-high power regimes have been explored aiming at growing high quality microcrystalline silicon at large deposition rates. The effect of the structural composition of the microcrystalline absorber layer on tandem device performance has been investigated. A preliminary evaluation of device stability has been done by exposing the tandem solar cells to white light for 200 hours. An initial efficiency of 11.3 % has been obtained. Keywords: Tandem, Micro Crystalline Si, Degradation. Pubblicazioni/2006/Micromorph 3DV.3.21.pdf P. Delli Veneri, L. V. Mercaldo, M. L. Addonizio, M. Ferrara, C. Privato Enea - Portici Research Center Località Granatello - 80055 Portici (Napoli) - Italy 55KB
18/05/2006 0.00.00 THE HYBRID LENS: A NEW CONCEPT TO CONCENTRATE THE SOLAR BEAMS The aims of this paper are the description of a new optical device created for C-modules, named “hybrid lens”, and its comparison with the prismatic lens. In the PhoCUS project, a prismatic lens has been designed and developed. Prismatic lens is made of an array of square refractive prisms of size 7,8x7,8 mm2 in the central portion, and 3,9x3,9 mm2 in the peripheral areas. The hybrid lens is made of prismatic refractive prisms in the central portion, and Fresnel grooves in the peripheral region. In this way, the prismatic portion of the lens creates a uniform distribution of solar beam on the cell and the Fresnel lens region increases the efficiency in the peripheral areas since the total length of Fresnel groves edges is shorter than that one of squared refractive prism in the prismatic lens. Simulations by the ray tracing software TracePro Expert have been carried out in order to evaluate the optical efficiency and the non-uniformity of the light flux on the target for the lens, without any kind of manufacturing defects. The optical efficiency has been estimated as 91% in the ideal case and as 84% considering manufacturing defects; it has been evaluated considering the ratio between the energy flux achieving the solar cell and that impinging on the external surface of the lens. Many indoor and outdoor tests have been carried out to determine the lens behaviour on the first prototype. These studies have shown that the hybrid lens potentially has an higher efficiency than the prismatic lens about of 5% in the peripheral areas. Keywords: Concentrators; Optical Losses; Ray Tracing Pubblicazioni/2006/Lens 5AV.3.15.pdf C. Cancro1, G. Graditi, M. Pellegrino, C. Privato, A. Romano, A. Antonini2 (1) ENEA R. C. Portici, Agenzia nazionale per le nuove tecnologie, l’energia e lo sviluppo economico sostenibile (ENEA). via Vecchio Macello, località Granatello, 80055 Portici (NA), Italia (2) Dipartimento di Fisica Università di Ferrara, via Paradiso 12, 44100 Ferrara, Italy mail to: carmine.cancro@portici.enea.it phone +39 081 7723278 fax +39 081 7723344 296KB
18/05/2006 0.00.00 PERFORMANCES CHARACTERIZATION OF CONCENTRATION SOLAR CELLS BY MEANS OF I-V AND LIFETIME MEASUREMENTS MADE WITH THE QSSPC TECHNIQUE In this work we compare the IV curves of concentration devices obtained with a standard solar simulator with that obtained using a PCD technique with the aim to extract resistive components of the cells. Different substrates and emitter doping profiles are analyzed. Results show that, at medium-high light concentration, where ohmic effects are relevant, the method we propose allows to easily measure the series and shunt resistance of the cells. Keywords: Concentration solar cells; series resistance. Pubblicazioni/2006/lifetime 2DV.2.8.pdf Santolo Daliento1, Luigi Mele1, Laura Lancellotti2, Pasquale Morvillo2, Eugenia Bobeico2, Franco Roca2 Luisa Pirozzi3. 1Dipartimento di Ingegneria Elettronica e delle TLC, Università “Federico II” di Napoli, Via Claudio 21, 80125, Napoli Italy, email: daliento@unina.it 2C.R. ENEA località Granatello, Portici, Italy, email: lancellotti@portici.enea.it, morvillo@portici.enea.it 3C.R. ENEA La Casaccia, Roma, Italy 415KB
17/05/2006 0.00.00 THIN FILM MODULES OPERATIONAL EXPERIENCE IN MEDITERRANEAN CLIMATE ENEA, the Italian National Agency for Energy and New Technologies within the frame of R&D and Demonstration activities of Photovoltaics in collaboration with KANEKA started a survey of building integrated a-Si thin film modules in order to test and compare their operational performance versus the other PV technologies and to collect data about their use in aggressive climatic conditions, such it can be for the near the sea installations, in Mediterranean climate. At first 1 kWp plant with a-Si single junction modules has been put in operation since June 2002 and then a second plant of 1 kWp with the new hybrid a-Si/μc-Si modules was installed at the beginning of January 2006. The paper reports the global and annual performance of both the plants data in order to make a comparison of array and modules of different size and technology with the other PV operational experience in the world. Data collected after a few years of continuous monitoring are shown for the previous plant. For the new plant we will report the experimental new storage data. This in-depth analysis is important since the thin-film technology is still in the process to gain a wider acceptance in the photovoltaic markets, due to the opened questions concerning its long term performance, the stability to the degradation, the reliability and expected lifetime that have contributed for the past to give a damaged image at the first module prototypes. Keywords: Building integration - 1: Thin film module - 2: Performance - 3: Environmental effect Pubblicazioni/2006/Kaneka 5BV_3_18.final.pdf F. Apicella1, V. Giglio1, M. Pellegrino1, S. Ferlito1, F. Tanikawa2, Y. Okamoto2 1 Centro Ricerche ENEA -Loc. Granatello - 80055 Portici (NA) - Italy Tel.+390817723400; Fax+390817723344; e-mail: felice.apicella@portici.enea.it 2 Kaneka Corporation - Osaka, 530-8288, Japan Tel. +81662265315 Fax +81662265144 201KB
16/05/2006 0.00.00 KEY ISSUES FOR THE IMPROVEMENT OF THE INTERFACE AND EMITTER QUALITY IN a-Si-:H/c-Si HETEROJUNCTION SOLAR CELLS The development of a cheaper, medium-thick polycrystalline ribbon silicon or similar material grown on glassily or other low cost substrates is an important topic of photovoltaic R&D to overcame the shortage of the Si feedstock is becoming a serious problem limiting further growth of PV market. The predicted materials impose low temperature approach for the surface passivation-conditioning and amorphous-crystalline silicon heterojunctions (SHJ) could be the solution. A necessary step toward further application of SHJ to the new class of materials is a better knowledge of the a-Si/c-Si interface structural, morphological and electrical modifications occurring during the various steps of the SHJ preparation. These steps include the c-Si substrate conditioning (wet and dry cleaning), the kinetics of SiH4-H2 based plasma ignition and the interaction with hydrogen-based species (H-atoms, Si-H, Si-H2, Si-H3 radicals) impinging and diffusing into the c-Si substrate. This contribution discusses the impact of the c-Si surface treatments on its interaction with hydrogen and on the interface and emitter quality in a-Si:H/c-Si heterojunction solar cells Keywords: Heterojunction, Silicon, Interfaces Pubblicazioni/2006/Heterojunction 3AO.8.2.pdf F. Roca1, E. Bobeico, M. Della Noce, P. Delli Veneri, L. Lancellotti, F. Formisano, L. Mercaldo, P. Morvillo, , M. M. Giangregorio, G.V. Bianco, A. Sacchetti, M. Losurdo, G. Bruno2 1ENEA Portici Research Centre – Località Granatello-80055 Portici (Naples) Italy Tel: +39081-7723 270; e-mail: roca@portici.enea.it 2Istitute of Inorganic Methodologies and of Plasmas, IMIP-CNR, Via Orabona 4, 70126 Bari, Italy Tel: +39080-5442094; e-mail: giovanni.bruno@ba.imip.cnr.it 357KB
15/05/2006 0.00.00 METAL GRID OPTIMIZATION OF C-SI SOLAR CELLS FOR CONCENTRATING SYSTEMS In the present work we have investigated the influence of metal grid on the cell performance of c-Si devices at one sun and under concentrated light. We have performed the modelling of the ohmic losses and different solar cells were realized by using metal grids having similar shadowing but different width and spacing between fingers. The first one was restricted to the lower values technologically feasible considering the future industrialisation of this process, namely transferring the concentration solar cell technology from lab-scale to prepilot level. The finger spacing was calculated and selected bearing in mind low shadowing and by taking into account the chosen finger width and height. The very high current level of this kind of devices imposed the use of thick fingers/busbar on the contacting structure in order to reduce the ohmic losses. We made a comparative study of the electrical behaviour of different devices (current-voltage and quantum efficiency characterization) at one sun and under concentrated light, to investigate the influence of different metal grid on the electrical performances of the devices. The best cell realized in our laboratory achieved the efficiency of more than 19.5% at 1 sun, 20.5% at 100 suns and more than 19% at 160 suns. Keywords: c-Si, Concentrator Cells, High Efficiency. Pubblicazioni/2006/Dresda 2006 PV-C Cell 1DV.1.13.pdf E. Bobeico, L. Lancellotti, P. Morvillo, F. Roca C.R. ENEA Portici Loc. Granatello, I-80055 Portici (Napoli), Italy 97KB
14/05/2006 0.00.00 A 9,6KWP DOUBLE AXIS PV SYSTEM INSTALLING HIT MODULES: TECHNICAL AND ECONOMICAL EVALUATION Regione Campania launched for the years 2000/2006 an operating program aimed to on-site power generation by means of both traditional and renewable sources in order to verify the technical and economical potentials for electrical energy generation and distribution. Many stakeholders joined the Project: Universities, Private Companies, Research Centers. Within this framework ENEA planned the installation in the Portici Research Centre of a 9,6kWp double axis Photovoltaic (PV) plant feeding an electrolyser for the hydrogen production. The focus of this work is to present the first experimental energetic results of the PV plant by comparing these data with those obtained by means of the numerical simulations. The PV generator includes 4 standard units of 2.4kWp each one at STC (Standard Test Conditions) and it is connected to the public low voltage electrical distribution network (230V, 50Hz) by two inverters. The standard unit is composed of 12 modules Sanyo Heterojunction with Intrinsic Thin (HIT) layer HIP-200NHE1 mounted on the double axis soloar tracker (Deger Tracker 1600EL). The HIT PV modules have been characterised by ENEA by means of a class A simulator at STC. Furthermore an economical analysis has been developed by the authors to compare the cost per kWh of the PV plant under investigation with the one of a fixed PV plant. Keywords: double axis PV system, HIT modules, energetic performance, economical analysis. Pubblicazioni/2006/CRdC 5BV.3.4.pdf G. Graditi, C. Cancro, M. Pellegrino, C. Privato, A. Scognamiglio ENEA R.C. Portici, Località Granatello, 80055 Portici (NA), Italy mail to: giorgio.graditi@portici.enea.it phone +39 081 7723400 fax +39 081 7723344 97KB
14/05/2006 0.00.00 Polymer protetto co password protetto Pubblicazioni/2006/Polymer substrates 3DV.3.32.pdf protetto 406KB
12/05/2006 0.00.00 ASSESSMENT OF THE PHOCUS /PV-C TECHNOLOGY: TECHNICAL FEATURES AND ECONOMICAL ASPECTS The main purpose of the PhoCUS (Photovoltaic Concentrators to Utility Scale) project performed by ENEA (Italian Agency for New Technologies, Energy and Environment) in close cooperation with some national industrial operators, was aimed to the development of a low-cost photovoltaic concentrators technology (PV-C technology) based on a medium concentration factor, to be applied in Mediterranean climates, like Southern Italy. The PhoCUS concentration factor, fixed at 200X , is achieved by means of a primary optics based on refractive lenses able to be integrated into the PV module. In the frame of the project, several technical problems was faced and overcome. In order to meet the low cost requirement a large use of conventional materials and components together with manufacturing and assembling techniques addressed to a cheap full automation have been adopted. The first phase of the project was completed. The efforts made brought to file many patents relating the novel solutions, as for the C-module, the optics, and the tracking control. The technical results coming from the experimental activities will be presented and discussed in the present paper. Their comparison with the expected values together with a detailed cost analysis will allow to make an intermediate assessment of the PhoCUS technology in order to outline the future activities. Keywords: Concentrator Cells, module, tracking Pubblicazioni/2006/5DO 7 4_new.pdf ASSESSMENT OF THE PHOCUS /PV-C TECHNOLOGY: TECHNICAL FEATURES AND ECONOMICAL ASPECTS 520KB
01/05/2006 0.00.00 BOOGIE-WOOGIE, A PHOTOVOLTAIC GLASS-GLASS MODULE “DANCING” WITH THE BUILDING The focus of this work – that is included in the Enea (Italian Agency for New Technologies, Energy and the Environment) activities in the field of the development of innovative building integrated photovoltaic components - is the development of an innovative photovoltaic module by means of tested industrial techniques, in order to allow a large scale production without increasing the costs. The project of a photovoltaic glass-glass module named “Boogie-Woogie” has been carried out and patented. The main feature of the component is its high aesthetic value depending on the design parameters, providing a relevant contribution to the improvement of the appearance of the building. In fact it can offer the designers the possibility of designing façades and coverings suiting a good quality of internal and external building spaces. It has been developed to be seen from the front side as well as from the back one, the cells pattern is random, and the electrical grids can contribute to a satisfying image of the component, ensuring a good satisfaction of designers, customers and users. An interesting field of utilization of Boogie-Woogie photovoltaic module can be identified with representative or symbolic buildings (especially public ones), where an important role is played by communicative aspects and by innovations acceptability. Keywords: building integration, façade, PV module Pubblicazioni/2006/Boogie 6DV 4 12.pdf A. Scognamiglio, G. Graditi, F. Pascarella, C. Privato mail to: alessandra.scognamiglio@portici.enea.it phone: +39 081 7723304 fax +39 081 7723344 ENEA R.C. Portici, località Granatello, 80055 Portici (NA), Italy 513KB
24/05/2005 0.00.00 TECHNOLOGY FOR THE PRODUCTION OF 20% EFFICIENCY C-SI SOLAR CELLS FOR CONCENTRATING SYSTEMS In the present work we have investigated the best working-conditions applied to crystalline silicon technology developed in ENEA laboratories to transfer the concentration solar cell technology from lab-scale to prepilot level. We have realized different devices using FZ p-type Boron doped wafers and varying the sheet resistance of the emitters aiming at analyzing the effects of junction depth and concentration on the surface of doped elements affecting the recombination process. The very high current level of this kind of devices (Jsc: 1 up to 8 A/cm2) imposed the use of thick fingers/busbar on the contacting structure in order to reduce the ohmic losses. Our aim is to develop a process easily transferable to industrial scale. A simplified photolitographic sequence to realize a thick layer of photoresist (>15 μm) followed by evaporation was used. We made a comparative study of the electrical behavior of different devices (current-voltage and quantum efficiency characterization) at one sun and under concentrated light, to investigate the influence of different fabrication conditions on the electrical performances of the devices. The best result achieved is η> 20% at 100 suns. Keywords: c-Si, Concentrator Cells, High Efficiency. Pubblicazioni/2005/Cella2CV.pdf E. Bobeico, G. Flaminio, G. Gerla, L. Lancellotti, N. Martucciello, P. Morvillo, F. Roca, C. Vernetti C.R. ENEA Portici, Loc. Granatello, I-80055 Portici (Napoli), Italy 142KB
21/05/2005 0.00.00 EXPERIMENTAL DETERMINATION OF THE DISSIPATION SYSTEM THERMAL BEHAVIOUR FOR CONCENTRATOR PHOTOVOLTAIC CELLS The use of concentrator solar cells in photovoltaic plants significantly reduces the number and area of expensive cells and contributes to reduce the total system cost. Unfortunately the remarkable power concentration weighing upon limited areas is only partially turned into electric energy; therefore its dissipation towards the outside becomes necessary. The characterization of the thermal dissipation structures used turns out to be necessary, in order to highlight its effectiveness in real working conditions. As the theoretical analysis of the heat transfer is a very complicated task, it is usual to obtain the total thermal resistance Rth (difference between the cell and the ambient temperature to the available irradiance on the cell) from experimental measurements. It has been realized an experimental apparatus with the aim of reproducing the thermal load conditions on a concentrator photovoltaic cell. By studying and comparing the thermal behaviours of various solutions, it is possible to come to the comprehension of the thermal phenomenon, so allowing the choice and the configuration of the best structure from the point of view of the performances/cost ratio. Keywords: Concentrator Cells, Thermal Performance, Experimental Methods Pubblicazioni/2005/DissipazioneTermica.pdf R. Fucci, G. Leanza, F. Pascarella, A. Romano, F. Roca ENEA Research Center Portici – Località Granatello 80055 – Naples – Italy, email:fucci@portici.enea.it 324KB
20/05/2005 0.00.00 IN SITU CONDUCTED EMISSSIONS ON THE GRID CONNECTED PV-SYSTEMS The paper presents the levels of conducted emissions, measured at the AC side terminals of a large grid connected photovoltaic plant, in pre-compliance regime. The conducted emissions - also named voltage noises - are voltages, present on the connection cables, with frequencies in the order of radio frequency. They are related to circulating currents - said noises currents or radio currents (IRF) - that can give electro magnetic interference when they appear on cables or structures with determined amplitudes. Using two different approaches the measurements have been made: one with the LISN, reading directly the conducted voltage stated by the standard and the other with the addition of a current probe at radio frequency. The conducted noises data are then compared to the limits of the standard CEI EN55014 for electric devices with more than 1000W of power. The survey was made within the general activity of ENEA for Photovoltaic System characterization. Keywords: 1) Large grid-connected PV-systems 2) EMC 3) In situ conducted measurements Pubblicazioni/2005/Emissioni.pdf G. Graditi, A. Matano, M. Pellegrino, R. Schioppo- ENEA Centro Ricerche, Località Granatello - 80055 Portici (NA), Italy, email to matano@portici.enea.it ENEA Centro Ricerche Area Sperimentale di Monteaquilone (FG), Italy 246KB
18/05/2005 0.00.00 RENOVATION OF SOCIAL HOUSES: A GOOD OPPORTUNITY FOR BUILDING INTEGRATED PV SYSTEMS The field of the building renovation represents at the moment one of the more interesting opportunity for the diffusion of BIPV, especially in countries like Italy where an huge heritage of buildings exists. A preliminary distinction has to be made between valuable buildings and standard or poor buildings, also referring to the different kinds of appropriate project approaches. The present work is focused on non valuable buildings, and particularly on the residential ones for the not-too-well-off people, called “social houses”, that are characterized by a rather poor technology and quality of the coverings (roof and especially facades). Generally interventions on the coverings are required in order to improve the energy performance of the envelopes and the comfort and satisfaction of the inhabitants. The project approach of the study is considering the PV systems not only as energy generators, but above all as an element of the general façade composition. So, the integration of photovoltaic devices in existing social houses is an excellent chance to reach a good appearance allowing a better satisfaction of the inhabitants, which is one of the more relevant aspects in planning social houses. Keywords: building integration: BIPV in renovation; BIPV aesthetic appeal; PV sun-shading devices. Pubblicazioni/2005/Facciata 6CV.2.17.pdf A. Scognamiglio1, G. Graditi1, P. Bosisio2, L. Pereira2 mail to: alessandra.scognamiglio@portici.enea.it; tel. +39 081 7723304; fax +39 081 7723344 1ENEA, C.R. Portici, località Granatello, 80055 Portici (NA), Italy 2DIPARC, Università degli Studi di Genova; Stradone S. Agostino 37, 16123 Genova, Italy 897KB
16/05/2005 0.00.00 THE PhoCUS STANDARD UNIT: DESIGN. REALIZATION AND PRELIMINARY PERFORMANCE ANALYSIS The PhoCUS (Photovoltaic Concentrators to Utility Scale) project was launched by ENEA (Italian Agency for the New Technologies, Energy, and Environment) in the late 2001 to develop, in close cooperation with national industrial operators, a low-cost photovoltaic concentrators technology. The road-map was outlined to get in short-medium term a system cost of 4.1€/Wp with a production of 5MW/year by assuming 20% as module nominal efficiency and 9% the incidence of the cell on the whole system cost. The design criteria of the standard unit, based on the applications of medium concentration refractive optics, permits to work singularly in connection with the low voltage grid and to be parallel connected each to other for a centralized power generation, The size was fixed at 5 kW in order to meet a distributed generation market demand and to limit the PV generator area to a single medium size tracking structure. Each PV C-system component was developed to assure opportunities be easy transferred to the production. The first standard unit prototype was installed in the first months of this year at Portici ENEA Research Center and the setting up and acceptance phase are in progress. The paper reports the lesson learned by the design, realization and installation of the system. Keywords: concentrators, PV module, PV system Pubblicazioni/2005/ImpiantoPhocusSU.pdf A. Sarno*, F.Apicella, C.Cancro, R. Fucci, F.Pascarella, M.Pellegrino, C.Privato and F. Roca Enea Portici Research Center Loc.Granatello 80055 Portici (Napoli) - Italy * phone +39 081 77 23 202 e-mail: sarno@ portici.enea.it 1.1MB
15/05/2005 0.00.00 A-SI THIN FILM MODULES: OPERATIONAL EXPERIENCE AND PERFORMANCE DEPENDENCY ON PV TECHNOLOGY AND ENVIRONMENT The paper presents preliminary performance data of roof integrated a-Si thin film modules that have been installed at a by-the-sea facility in Mediterranean climate for testing their behavior in aggressive climatic conditions. The annual energy production has been used for the survey since it is the most useful indicator of performance in real operating conditions, in addition of providing the basis for the photovoltaic system design. The experiment aimed to look at the main barriers for a-Si thin film technologies and to provide a better understanding. The project was planned to evaluate the reliability of the modules efficiency in terms of capacity to maintains the energy conversion efficiency over long periods and the behaviour of the modules structures subjected to the hard marine environment conditions (temperature, corrosion etc.). An accurate monitoring system of the environmental parameters and of the generated power has been used to evaluate the effects of the primary factors. Data collected after a few years of continuous monitoring are shown. Keywords: Degradation, a-Si, Performance, Environmental Effect Pubblicazioni/2005/KANEKA.pdf F. Apicella1, V. Giglio1, M. Pellegrino1, S. Ferlito1, G. Flaminio1, Y. Okamoto2, F. Tanikawa2 1 Centro Ricerche ENEA - Agenzia nazionale per le nuove tecnologie, l’energia e lo sviluppo economico sostenibile. Loc. Granatello - 80055 Portici (NA) - Italy Tel.+390817723400; Fax+390817723344; e-mail: felice.apicella@portici.enea.it 2 Kaneka Corporation - Osaka, 530-8288, Japan 171KB
14/05/2005 0.00.00 DESIGN, REALIZATION AND PRELIMINARY PERFORMANCE ANALYSIS OF THE PhoCUS -5 STANDARD UNIT The main scope of PhoCUS (Photovoltaic Concentrators to Utility Scale), launched by ENEA (Italian Agency for Energy, New technologies and Environment) and partially supported by the Italian University and Research Ministery (MIUR) is to develop, in close cooperation with industrial operators, a low-cost photovoltaic concentrators technology (C-technology) to be applied in Mediterranean climates, like Southern Italy. The road-map of the project was outlined to get in medium term a system cost of 4.1€/Wp with a production of 5MW/year and assuming 20% as module nominal efficiency and 9% the incidence of the cell on the whole system cost. One of the main objectives of the PhoCUS is the development, the design and the realization of the standard unit based on a medium concentration factor to be achieved by means of refractive lenses able to be integrated into the PV module. The installation of the standard unit first prototype at Portici ENEA Research Center was completed in the first months of this year. At present, the setting up and acceptance phase are in progress.The paper will report the lesson learned by the design, realization and installation of the system. The results coming from specific experimental campaigns both on single component and on whole system will be presented and discussed Keywords: concentrators, supporting structure, PV module Pubblicazioni/2005/PhocusArizona.pdf A. Sarno*, F. Apicella, C.Cancro, R.Fucci, M.Pellegrino, C.Privato, F.Roca Enea Portici Research Center Loc.Granatello 80055 Portici (Napoli) - Italy * phone +39 081 77 23 202 e-mail: sarno@ portici.enea.it 243KB
13/05/2005 0.00.00 Plastic Structured Optics for Solar Concentrators in PV Systems The main advantages of using plastic structured optics for concentrating solar beams on a receiver of a PV system, instead of more traditional materials like glass and quartz, rely on very large mass production, improved structured optics design and manufacturability, reduced weight, high optical quality, low unit cost. ENEA in the framework of PhoCUS (Photovoltaic Concentrators to Utility Scale) Project has investigated both prismatic (patented) and multi-foci Fresnel PMMA (polymethylmethacrylate) optics. Among all the molding technologies, the injection process has been selected to produce these optics. Some critical parameters of manufacturing process have been investigated in order to improve the aspect ratios and the optical quality of the molded prismatic lens. The resulting samples for this type of lens appear to have a reduced stress, satisfactory planar surfaces and a small radius of curvature for rounded corners, corresponding to a good optical efficiency (major than 80%). The results obtained with the multi-foci Fresnel lens have been less adequate. The first production of prismatic lens has been employed to realize the PhoCUS C-module prototypes, presently under outdoor testing. Further improvement is expected with the deposition of an antireflective hard coating on the incoming surface. Pubblicazioni/2005/PlasticStructuredOptics.pdf C. Privato, C. Cancro, M. Pellegrino and Angelo Sarno ENEA Centro Ricerche Località Granatello I-80055 Portici (NA), Italy. e-mail: carlo.privato@portici.enea.it tel: +39-81-7723-273 fax: +39-81-7723-493 890KB
12/05/2005 0.00.00 ELECTRICAL CHARACTERIZATION OF POINT FOCUS CONCENTRATOR PHOTOVOLTAIC CELLS THROUGH INDOOR AND OUTDOOR MEASUREMENTS Photovoltaic (PV) cells and modules are often rated in terms of a set of standard reporting conditions defined by temperature, spectral irradiance, and total irradiance. As photovoltaic devices operate on a wide range of temperatures and irradiances, the temperature and irradiance –related behaviour must be known. The use of flash solar simulators allows the characterization of any kind of receivers; the energy that the cell receives during the measurements is negligible and it doesn’t change the value of the temperature appreciably. But concentration level and lack of uniformity affect the various working variables (Voc, Iscc, η, FF) in such a way that is not the same for all cells and lenses; to evaluate the real space distribution effect of the luminous energy on the characteristics of the cell, an experimental apparatus for outdoor measurements has been realized, and a series of measurement techniques has been executed on the cell in order to evaluate the performances of a PV-C cell. Keywords: Concentrator Cells, Characterization, Experimental Methods Pubblicazioni/2005/CaratterizzazioniElettriche.pdf R. Fucci, G. Flaminio, G. Leanza, A. Romano, F. Roca ENEA Research Center Portici 300KB
12/05/2005 0.00.00 RADIOMETER FOR CONCENTRATED SOLAR RADIATION We describe a novel radiometric method and apparatus, suitable for both total power and spatial intensity profile measurement of concentrated solar radiation. The radiation is collected by a first optical cavity, where it is integrated and attenuated. A portion of this radiation is driven, through a window with selected aperture area, to a second optical cavity where it is integrated and attenuated for the second time. In the second cavity the solar radiation intensity is measured using a conventional low flux density radiometer and spectrally analyzed using a conventional spectrometer. The proper selection of the intermediate window aperture allows the level of radiation intensity at the input to be regulated and very high levels of attenuation can be obtained, in the order of thousands. When used for intensity profile measurements, the radiometer is moved by an x-y translation stage to draw the 2D map of intensity. Pubblicazioni/2005/Radiometro.pdf A. Parretta*1, M. Pellegrino1, G. Flaminio1, S. Bolognesi1, G. Nenna1 1ENEA Research Centre, Località Granatello, 80055 Portici (Na), Italy. *Phone: +39 (0)81 7723262; Fax: +39 (0)81 7723344; E-mail: antonio.parretta@portici.enea.it 253KB
11/05/2005 0.00.00 REFLECTANCE AND TRANSMITTANCE INDOOR TECHNIQUES FOR TESTING CONCENTRATING LENSES The technical and economical success of the concentrating PV systems relies, beyond other important primary factors as cells efficiency, tracking precision and module assembly quality, also on the device good optical performance for efficiently directing solar rays on the receiver. In fact the proper lens should meet many different requirements: it has to be very well designed and realized, made of a material with high optical grade properties and cheap, good to withstand the environmental causes of degradation and durable. ENEA launched the PhoCUS (Photovoltaic Concentrators to Utility Scale) Project in the late 2001 for medium concentration, 200X, in order to investigate the photovoltaic concentrators technologies and to assess the technical and economical feasibility of this application in Italy for the electrical energy generation. The cost effectiveness success of this project goes necessary through the optical device good realization. So testing the optical efficiency of the lenses in a reliable and easy way is crucial for making an early assessment of their quality and capability to reach the ultimate project purpose. Keywords: Concentrators, Characterisation, Optical Losses Pubblicazioni/2005/Riflettanza.pdf M.Pellegrino, S. Bolognesi, G. Flaminio, C. Privato, A.Romano and A. Sarno ENEA Research Centre, Località Granatello, 80055 Portici (Na), Italy. Phone: +39 (0)81 7723262; Fax: +39 (0)81 7723344; e-mail: michele.pellegrino@portici.enea.it 253KB
10/05/2005 0.00.00 SOE AND ASSEMBLY METHODOLOGY: HOW TO REDUCE THE LOSSES AND THE COSTS IN A CONCENTRATION MODULE The Authors focus on the description of an analytical method in order to analyse the optic losses in a concentration module and the constructive improvements to minimize its. The first part of the paper concerns a detailed analysis about the constructive, assembling and dimensional aspects of a C-module; in particular has been analyzed the Cmodule of PhoCUS project as a reference case [1]. The module architecture consists on: the heat sink, the cell, the housing and the lens-parquet. The values of dimensional tolerances of the above components have been measured and the centring tolerance of cell on the heat sink, that one of parquet on the housing has been defined. In the second part of the paper the optic misalignment aspect has been analyzed. The displacement and the deformation of optic spot, due to a solar tracker mistake, have been studied. The results, which are in experiments, show the optical losses on the cell are due to the matched effects of alignment and tracking errors. Subsequently, the planning of a Secondary Optical Element (SOE) and the constructive solutions have been described. SOE is able to deflect the luminous beams coming from the disc on cell area with an error of tracking of +1°. Different tests, by means constructed prototypes handicraft of SOE, have been carried out. The use of SOE gives the following benefits: decreasing of precision demanded to the solar tracker, protection of plastic housing from dangerous outside fire, reduction of the intrinsic losses in the case of non-optimal tracking, uniformity of energy flux over the cell [2] and a small decrease of the system global cost. KEYWORDS: Concentrators, optical losses, economical analysis. Pubblicazioni/2005/SOEmethodology.pdf C. Cancro, R. Fucci, G. Graditi, C. Privato, F. Roca, A. Romano, A. Sarno ENEA Centro Ricerche, Località Granatello - 80055 Portici (NA), Italy tel:+390817723111; fax:+390817723344 email: carmine.cancro@portici.enea.it 253KB
09/05/2005 0.00.00 DESIGN OF VERTICAL SUNSHADING PV SYSTEMS FOCUSED ON PHOTOVOLTAIC The main focus of the authors is on providing architects, planners and designers with an easy tool allowing a preliminary design of fixed photovoltaic sun-shading devices. The approach is formulating some criteria focused on photovoltaic performance, but some preliminary conditions have been established in order to evaluate only the possibilities representing a good balance between the different functions (sun-shading and photovoltaic generator). Particularly a conceptual model of a vertical PV sun-shading system has been designed so that on June 21 (maximum annual Sun elevation) it matches two conditions: the shading effects over the lamellas are avoided, and the interior is well shadowed by the sunshade. In order to establish the minimum respective distance between lamellas (pitch) a mathematical relation depending on the geographical site (latitude) has been determined; it links all the different parameters that have to be considered during the design process. Various alternatives have been analysed referring to a fixed South-oriented façade and changing parameters like: latitude, lamellas width, pitch and tilt, sunshade tilt and distance from the facade. The results have been collected into some abacus, and the electrical performances of the different cases have been predicted using a simulation code, and then evaluated by means of appropriate factors. Keywords: building integration, PV sun-shading device Pubblicazioni/2005/Sunshading.pdf A. Scognamiglio1, G. Graditi1, P. Bosisio2, E. A. Cordasco3 mail to: alessandra.scognamiglio@portici.enea.it; tel. +39 081 7723304; fax +39 081 7723344 1ENEA C. R. Portici, Loc. Granatello - 80055 - Portici, Italy 2DIPARC, Università degli Studi di Genova, Stradone S. Agostino 37 - 16123 - Genova, Italy 3Facoltà di Ingegneria, Università Federico II, P.le Tecchio 80 - 80125 - Napoli, Italy 173KB
08/05/2005 0.00.00 TOOLS FOR AN EFFICIENT POLICY OF PV IN URBAN PLANNING Policy makers and administrative bodies are to prepare regional or local energy plans for their territories. As photovoltaic energy, among other renewable sources, has a great potential to be largely and widely used while integrating built environment and infrastructures under their jurisdictions, reliable tools should be deployed in order to make the task easier and to get complete and detailed plans for intervention. In addition to the land aerial photos so far largely used by municipalities for exploration and use of territory for different applications, other than BIIPV integration, the efficient use of Geographic Information Systems - at a local, Regional, National or even International level- maybe also using satellite data for preliminary rough estimates, may provide help for useful and accurate analyses. Such an approach relies on already achieved results for biomass, geothermal and wind energy potential assessment and exploitation; the paper shows a specific new Building and Infrastructures Photo Voltaic Geographic Information System (BIIPV-GIS) tool for distributed urban scale PV sources integrated to buildings and infrastructures, carried out on a little case-study to prove if dynamic multi-criteria above mentioned methodology could be successfully deployed, giving same effective and useful results in terms of urban planning, even at a larger scale. Keywords: 1. Building and Infrastructures Integration 2 Energy Options 3Policy making Pubblicazioni/2005/ToolsUrban.pdf M. Pellegrino1, D. Gomez Gane3, L. Nibbi2, G. Tondi2 1ENEA Research Centre, Località Granatello, 80055 Portici (Na), Italy. *Phone: +39-81-7723262, Fax: +39-81-7723344, e-mail: michele.pellegrino@portici.enea.it 2ETA Renewable Energies, Piazza Savonarola 10 - 50132 Florence, Italy Phone +39-055-5002174, Fax +39-055-573425, e-mail: leonardo.nibbi@etaflorence.it, gianluca.tondi@etaflorence.it 3 La Sapienza University, Faculty of Architecture, Piazza Borghese 9- 00186 Rome, Italy Phone: +39-06- 49918870, Fax: +39-06- 49918873 e-mail:dgomezgane@yahoo.it 36KB
04/11/2004 0.00.00 Current-voltage characteristics of high-efficiency silicon solar cells from photoluminescence Series resistance is a fundamental power-limiting factor for a solar cell. It is known to depend on the ohmic losses due to the metal contact resistance, the metal–semiconductor contact resistance, the substrate resistance, and the emitter sheet resistance. A typical operating approach consists of indirect measurements of the total series resistance. Our method, based on photoluminescence, is capable of generating an illuminated current–voltage curve free from the effect of the contact series resistance, giving an immediate idea of true cell performance. © 2004 American Institute of Physics. Pubblicazioni/2004/APL2.pdf L. Ferraioli and P. Maddalenaa) INFM-COHERENTIA, Dipartimento di Scienze Fisiche, Università di Napoli “Federico II,” Via Cintia, I-80126 Napoli, Italy A. Parretta ENEA Centro Ricerche Portici, Località Granatello, I-80055 Portici (Na), Italy A. Wang and J. Zhao Centre for Photovoltaic Engineering, University of New South Wales, Sydney NSW 2052, Australia 53KB
07/10/2004 0.00.00 Evidence for generalized Kirchhoff’s law from angle-resolved electroluminescence of high efficiency silicon solar cells. The angular distribution of infrared radiation, emitted by high efficiency single-crystalline silicon solar cells, was analyzed. Measurements were performed on cells with planar and inverted-pyramids surfaces, both showing integral emissions that approach the cosine function in the 0°–90° interval. Textured cell maintains the cosine distribution at the different wavelengths; planar device shows a distribution, which deviates from the cosine function at increasing wavelength. Correspondence between emission and absorption properties was demonstrated valid as a function of emission/ absorption angle. From the angular distribution of electroluminescence light, the devices absorption properties for incident light with directions different from the surface normal were estimated. Pubblicazioni/2004/APL02484.pdf L. Ferraioli and P. Maddalenaa) INFM-COHERENTIA, Dipartimento di Scienze Fisiche, Università di Napoli “Federico II,” Via Cintia, I-80126 Napoli, Italy E. Massera and A. Parretta ENEA Centro Ricerche Portici, Località Granatello, I-80055 Portici (Na), Italy M. A. Green Centre for Third Generation Photovoltaics, University of New South Wales, Sydney NSW 2052, Australia A. Wang and J. Zhao Centre for Photovoltaic Engineering, University of New South Wales, Sydney NSW 2052, Australia 55KB
07/10/2004 0.00.00 Optical degradation of long-term, field-aged c-Si photovoltaic modules The optical degradation induced by long-term (about 15 years) field exposure on c-Si photovoltaic modules belonging to the large-scale Delphos ENEA PV plant, located in Manfredonia (South of Italy), was investigated by making comparative reflectance measurements on the exposed modules, after their dismounting and cleaning, and on the original, unexposed counterparts. Four types of module fabrication technologies were analyzed: Helios single-Si, Pragma single-Si, Pragma multi-Si and Ansaldo multi-Si. Siemens multi-Si modules, of recent technology and exposed for 5 years, were taken as reference. The electrical loss measured for the single PV generators of the Delphos plant, each corresponding to a particular module technology, after a monitoring period of about 10 years, resulted to range between 11–22% for the output power and 9–14% for the output current. The aging effects on the dismounted and cleaned modules appeared as the discoloration of ARC layer, particularly at the center of the cells, and as the formation of stains distributed over the cell surface, likely due to the browning of the EVA. The spectral measurements of the total hemispherical reflectance, carried out under direct light at near-normal incidence, showed that the discoloration of ARC is associated to a decrease of the reflectance in the blue region (400–500 nm), and a resulting levelling of the spectral reflectance curves. The spectrally integrated measurements of reflectance carried out at diffuse white light, on the other hand, have provided evidence of an increase of the total hemispherical reflectance for exposed modules, particularly marked for the multi-Si modules, which correlates quite well with the extent of current loss measured on the single PV generators of Delphos plant. Pubblicazioni/2004/SOLMAT3420.pdf Antonio Parrettaa, Mariano Bombacea, Giorgio Graditia, Riccardo Schioppob 563KB
29/09/2004 0.00.00 AMORPHOUS/CRYSTALLINE SILICON HETEROSTRUCTURE SOLAR CELL: SIMULATION AND EXPERIMENT In this work we report on the technological steps of the process we used to obtain high efficiency heterostructure solar cell. The device is based on a cast production p-type monocrystalline silicon and on a n-type amorphous silicon deposited by PECVD technique. An ad-hoc treatment has been performed on the top of the n layer in order to increase the built-in voltage of the structure. This increase leads to a better collection of photogenerated carries at the maximum power point of the cell. A numerical device simulator has been utilized to explain the increase of device performances. Photovoltaic efficiency equal to 17% is obtained on a 2.25 cm2 total area device. This represents the highest value in heterojunction solar cell based on p-type crystalline silicon. Keywords: a-Si; Heterojunction; Solar Cell Efficiencies; Pubblicazioni/2004/ParigiHJ.PDF G. de Cesare1, D. Caputo1, M. Tucci2 1 Electronic Engineering Dpt, University of Rome "La Sapienza", via Eudossiana 18, 00194 Roma, Italy 2 Enea Research Center Portici, località Granatello, 80055 Portici, Napoli, Italy 204KB
29/09/2004 0.00.00 MPPT CIRCUIT FOR PV SYSTEM FOR LOW POWER PORTABLE APPLICATIONS In this work we have designed, fabricated and tested a Maximum Power Point Tracking (MPPT) circuit for photovoltaic systems suitable for low power, portable applications with resistive load. This type of load allows to simplify the design of the MPPT system, satisfying the specifications of low-cost, small size and low power consumption required by this application. The operation principle was proven simulating the circuit at block level by using Simulink. A photovoltaic system with and without the proposed MPPT circuit was tested on a 2 Ω resistor as well as on a camping refrigerator. Keywords: Stand-alone PV-system, tracking, MPPT Pubblicazioni/2004/ParigiMPPT.pdf G. de Cesare, D. Caputo, A. Nascetti, M. Tucci* Department of Electronic Engineering, University of Rome “La Sapienza” via Eudossiana, 18 - 00184 Rome (Italy) *ENEA Research Center via Vecchio Macello, Località Granatello, Portici, Naples, (Italy) 261KB
01/07/2004 0.00.00 PROTON INDUCED DAMAGE OF AMORPHOUS/CRYSTALLINE SILICON HETEROJUNCTION SOLAR CELLS Current-voltage under illumination and quantum yield characteristics of an amorphous silicon/crystalline silicon hetero solar cell have been measured before and after exposure to high energy (1.7MeV) protons. A comparison of the measured wavelength dependent quantum yield with calculated values enabled to determine the effective electron diffusion length of the crystalline silicon, that dropped from a value of 434mm before to a value of 4mm after irradiation with 5.1012cm-2 protons. Good agreement has been obtained between measured and simulated data using, DIFFIN, a finite element simulation program for a-Si:H / c-Si heterojunctions solar cells, enabling us to extract the depth profile of the recombination rate and the density of states distribution in the semiconductor layers before and after irradiation. Keywords: Heterojunction, Lifetime, Radiation Damage Pubblicazioni/2004/Parigi8AV34.pdf Heinz-Christoph Neitzert 1, Francesco Roca 2, Patrizio Spinillo 1, Mario Tucci 2 1 DIIIE, Università di Salerno, Fisciano (SA), Italy Tel: +39-089-964304, fax: +39-089-964218, e-mail: neitzert@unisa.it 2 Centro Ricerche Portici, ENEA, Portici (NA), Italy Tel: +39-081-7723270, fax: +39-081- 7723344, e-mail: roca@portici.enea.it 251KB
29/06/2004 0.00.00 AN EXPERIMENTAL ANALYSIS OF POWER QUALITY IN PRESENCE OF SINGLE PHASE GRID CONNECTED PHOTOVOLTAIC SYSTEMS In this paper an experimental power quality analysis in presence of single phase grid connected PV systems is performed in a PV system installed at the Department of Electric Engineering of the University of Palermo through a measurement system set up by the Authors. In particular the analysis has been carried out focusing the attention on voltage and current distortion, as the solar radiation varies. The corresponding Total Harmonic Distortions in voltage and current terms are reported and compared with the standards limits. The presence of interharmonic components is also discussed. Keywords: Small Grid-connected PV Systems, Inverter, Power Quality. Pubblicazioni/2004/Parigi5BO96.pdf G. Graditi(1,2), S. Favuzza(2), E. Riva Sanseverino(2), G. Vitale(3) (1) Centro Ricerche ENEA - Agenzia nazionale per le nuove tecnologie, l’energia e lo sviluppo economico sostenibile (ENEA). Via Vecchio Macello – 80055 Portici (Napoli) – ItaliaTel.+390817723400; Fax+390817723344; email: giorgio.graditi@portici.enea.it (2) Dipartimento di Ingegneria Elettrica – Università di Palermo Viale delle Scienze – 90128 Palermo (Italia) Tel.+390916615221; Fax+39091488452; email: favuzza,eriva@diepa.unipa.it (3) ISSIA (Istituto sui Sistemi Intelligenti per l’Automazione) – CNR, Sezione di Palermo Viale delle Scienze – 90128 Palermo (Italia), Tel.+39091484686; Fax+39091485555, email: vitale@cerisep.pa.cnr.it 295KB
29/06/2004 0.00.00 EXCIMER LASER INDUCED CRYSTALLISATION OF HYDROGENATED AMORPHOUS SILICON-CARBON FILMS Excimer laser treatments have been carried out on hydrogenated amorphous silicon-carbon with carbon content, x = C/(C+Si), in the 0.08-0.28 range varying the fluence from 64 to 242 mJ/cm2. Silicon crystallites have been induced in the samples independently of the alloy composition, while SiC crystallites have been detected in samples with x ≥ 0.18 irradiated at fluences greater or equal than to 188 mJ/cm2. The crystalline volume fraction increases as a function of carbon content in the films. After laser irradiation all the films have shown a noticeable increase in dark conductivity, and a considerable modification of the optical properties. The effects of laser annealing on the crystallisation process appear to be correlated with the optical properties of the as deposited films. Keywords: Laser processing– 1: crystallisation –2: Silicon Carbon alloys- 3. Pubblicazioni/2004/Parigi3DV142.PDF U. Coscia1, G. Ambrosone1, C. Minarini2, V. Parisi3, S. Schutzmann4, A. Tebano5, P. Rava6, C. Privato2, P. Delli Veneri2 1INFM-Dipartimento di Scienze Fisiche, Complesso Universitario di Monte S. Angelo, via Cintia, I-80126 Napoli, Italy 2ENEA Research Center – Loc. Granatello, I-80055 Portici, Napoli, Italy 3INFM-Dipartimento di Medicina Sperimentale e Patologia, Università di Roma “La Sapienza” I-00161 Roma, Italy 4INFM-Dipartimento di Scienze e Tecnologie Fisiche ed Energetiche, Università di Roma “Tor Vergata”, Via di Tor Vergata 110, I-00133 Roma. 5INFM-Dipartimento di Scienze e Tecnologie Chimiche, Università di Roma “Tor Vergata”, Via della Ricerca Scientifica 1, I-00133 Roma 6Elettrorava Spa, 10040 Savonera, Torino 251KB
29/06/2004 0.00.00 EFFECTS OF BIPV ON PERFORMANCES The effect on performances of both module temperature and non optimal array exposure will be analysed. In this paper the five investigated grid connected PV systems are installed or integrated in buildings (mainly Municipalities, Universities, Secondary Schools) at different geographical location and are representative of the basic ways of mounting: namely roof, facades, canopy sunshade and free standing on flat roof. A special emphasis has the localization of modules, characterized by high visibility for people and an educative value for students. Of course, in order to analyze plant performance and to verify the effectiveness of the adopted technical solutions, all the pilot plants have been routinely monitored. The results of the analysis confirm the importance of the optimal mounting exposition as well as best solutions for an efficient cooling of the PV modules. Keywords: Building Integration, Performance, Evaluation Pubblicazioni/2004/Parigi5BV222.pdf A. De Lillo, Saverio Li Causi, Salvatore Castello, Francesco De Lia, Giorgio Graditi*, Alessandra Scognamiglio* ENEA C.R. Casaccia, Via Anguillarese 301 - 00060 - Rome, Italy * ENEA Portici, Loc. Granatello – 80055 - Portici, Italy 482KB
29/06/2004 0.00.00 TECHNICAL AND ECONOMICAL ASPECTS ON INTEGRATED PV-UPS SYSTEMS This paper shows a technical-economical analysis of a novel Uninterruptible Power Systems (UPS) configuration, in which the backup batteries would be replaced by a photovoltaic (PV) system. Many interesting technical and economical issues concerning the proposed configuration are discussed against the traditional UPS and backup batteries solution. Moreover the technical solutions concerning the proposed integrated system realized using a double conversion UPS are motivated. Finally the operating costs of the proposed integrated PV-UPS system and the classical system with UPS and batteries with different sizes, and as the back-up time varies, are also compared and interesting results have been observed. Of course, the costs estimation for systems including renewables is not easy and cannot be precise, especially on the mid and long term, but still the analysis carried out shows that the proposed system seems to be an economically convenient choice at present in many cases and in the near future almost in all cases. Keywords: Economic Analysis, Batteries, Integrated PV-UPS Systems. Pubblicazioni/2004/Parigi5BV241.pdf G. Graditi1,2, F. Apicella1, A. Augugliaro2, L. Dusonchet2, S. Favuzza2, E. Riva Sanseverino2 1 Centro Ricerche ENEA - Agenzia nazionale per le nuove tecnologie, l’energia e lo sviluppo economico sostenibile (ENEA). Via Vecchio Macello - Località Granatello - 80055 Portici (Napoli) - Italia Tel.+390817723400; Fax+390817723344; email:giorgio.graditi@portici.enea.it 2 Dipartimento di Ingegneria Elettrica - Università di Palermo Viale delle Scienze - 90128 Palermo (Italia) Tel.+390916615221; Fax+39091488452; email: augugliaro,dusonchet,favuzza,graditi,eriva@diepa.unipa.it 132KB
29/06/2004 0.00.00 POWER CONDITIONING: EXPERIMENTAL TESTS TO COMPARE DIFFERENT PV - GRID INTERFACES The paper focuses on a comparison among grid-connected inverters with different sizes, technologies and PV system layouts. The comparison is based on experimental tests, where the input powers are normalised with respect to the nominal values, in order to determine a set of meaningful parameters both in laboratory and in field operation. The inverters under study in laboratory include one centralised inverter, one string inverter which has three separated MPPT, one per string, and two module integrated inverters. About the PV systems in field operation, four plants have been analysed, three with 20 kWp and one with 16 kWp power. The experimental results show that some specifications are not fulfilled, particularly those about MPPT efficiency (due to high DC ripples and ineffective MPP algorithm) and THD of currents injected into the grid. Keywords: 1 Experimental Methods , 2 Inverter , 3 Grid-Connected Pubblicazioni/2004/Parigi 5BV119.pdf G. Graditi(1,2), V. Cataliotti(1), R. Napoli(3), F. Spertino(3) (1) Università di Palermo - Dipartimento di Ingegneria Elettrica Viale delle Scienze - 90128 Palermo, Italy Tel: +39091-6615221; fax: +39091-488452 - Email: graditi,cataliotti@diepa.unipa.it (2) Centro Ricerche ENEA – Agenzia nazionale per le nuove tecnologie, l’energia e lo sviluppo economico sostenibile (ENEA). Via Vecchio Macello - 80055 Portici, Napoli, Italy Tel: +39081-7723400; fax: +39081-7723344 - Email: giorgio.graditi@portici.enea.it (3) Politecnico di Torino - Dipartimento di Ingegneria Elettrica Corso Duca degli Abruzzi 24 - 10129 Torino, Italy Tel: +39011-5647105; fax +39011-5647199 - Email: filippo.spertino@polito.it 736KB
14/06/2004 0.00.00 SILICON HETEROJUNCTION CELLS R&D IN EUROPE Europe has a leading position in the production of crystalline ingots and wafers for PV applications. The development of a cheaper, medium-thick polycrystalline ribbon silicon or similar silicon materials is an important topic of photovoltaic R&D. The chemical-physical properties of the predicted material involves the risk of degradation of minoritycarrier lifetimes associated with high-temperature processes and imposes a new approach to realize the junction. The decrease in active-layer thickness requires novel concepts for light trapping, correspondingly and the roughness of the surface requires specific and more efficient surface treatment for passivation. The amorphous silicon (a-Si)/monocrystalline silicon (c-Si) Heterojunction with Intrinsic Thin-layer (HITTM) solar cell developed by Sanyo Electric was applied successfully to c-Si and offers many excellent features for the solution of the indicated issues, but the potential of Silicon Heterojunction (SHJ) technology on thin silicon is not totally explored. This paper gives an overview about the current R&D activities in Europe dealing with the SHJ technology as well as the perspective for short mid term application on thin silicon. Keywords: Silicon-1: Thin Solar cells-2: Heterojunction-3. Pubblicazioni/2004/Parigi 3BP.1.1.pdf F. Roca1, J. Cárabe2 & A. Jäger-Waldau 3 1ENEA Portici Research Centre – Località Granatello-80055 Portici (Naples) Italy. Tel: +39081 7723 270; fax:+39081-7723344; e-mail:roca@portici.enea.it 2CIEMAT DER – Avda. Complutense, 22 E-28040 Madrid. Spain Tel: +34.913466047; fax: +34.913466037; e-mail: julio.carabe@ciemat.es European Commission DG JRC- Via E. Fermi 1; TP 450 I.- 21020- Ispra (VA) Italy tel: +39 0332 78-9119 Fax:+39 0332 78-9268 e-mail: arnulf.jaeger-waldau@cec.eu.int 985KB
07/06/2004 0.00.00 THE FIRST PROTOTYPES OF THE PhoCUS PROJECT: DESIGN AND PRELIMINARY PERFORMANCE ANALYSIS The main purpose of the PhoCUS (Photovoltaic Concentrators to Utility Scale) project is to develop a photovoltaic concentrators technology (C-technology) in order to demonstrate the technical feasibility of this application in Italy and to assess its greater potentials to drive a reduction of the PV System investment cost. The road-map of the project was outlined on the basis of a detailed feasibility study aimed at identifying the most promising technologies to get in medium term a system cost of 4.1€/Wp with a production of 5MW/year. During the first phase of the project the efforts have been addressed to develop and optimise the most appropriate technologies for devices and components with particular attention to the C-module and the tracking structure. The development of the above mentioned components, as well as the prototypes design and realization, has been performed by Enea in close cooperation with two qualified national industrial operators, namely Eni -Tecnologie (formerly Eurosolare) and Galileo Avionica. The paper will illustrate the technical approach and the main design criteria followed in order to meet the technical and economical requirements. A detailed analysis, based on both experimental and computational results, shows that the prototypes performance is in good agreement with the expected one. A preliminary economic analysis, based on the cost of the prototyopes, at present under construction, demonstrates that the components standardization together with an improvement of the process automation can give a significant contribute in meeting also the target cost. Keywords: concentrators, module, tracking Pubblicazioni/2004/Parigi5BV147.pdf M. Avitabile, C.Cancro, G.Contento, R. Fucci, F.Roca , C.Privato and A. Sarno* F.Ferrazza°, M.Zarcone°, M.Ceccherini°° Enea Portici Research Center Loc.Granatello 80055 Portici (Napoli) - Italy ° EniTecnologie (formerly Eurosolare) Nettuno (Roma) Italy, °° Galileo Avionica Firenze Italy * phone +39 081 77 23 202 e-mail: sarno@ portici.enea.it 203KB
04/06/2004 0.00.00 INFLUENCE OF VHF PECVD MICROCRYSTALLINE SILICON PROPERTIES ON SOLAR CELL PERFORMANCES Intrinsic microcrystalline silicon was deposited by Very High Frequency Plasma Enhanced Chemical Vapor Deposition (VHF PECVD) at a frequency of 100 MHz. The substrate temperature was varied in the range 100 – 220 °C. Different gas mixtures of silane and hydrogen were utilized, while keeping the plasma power at 20 W and the chamber pressure at 950 mTorr. The material was characterized by means of electrical and optical properties. Different intrinsic active layers were inserted into p-i-n microcrystalline solar cells while keeping constant the deposition parameters of the doped layers. In particular, the effects of the active layer deposition temperature and hydrogen dilution on the spectral response of the solar cells were analyzed. A correlation was found between the properties of the single layer and the performance of the devices. The effect of the active layer thickness was also studied. An efficiency of 6% was reached with a Fill Factor of about 60%. Keywords: Thin Film, Micro Crystalline Si, Spectral Response. Pubblicazioni/2004/Parigi3DV117.pdf P. Delli Veneri , L. V. Mercaldo, E. Bobeico, P. Spinillo, C. Privato ENEA - Portici Research Center Località Granatello, 80055 Portici (Napoli), Italy Phone: +39 081 7723259; Fax: +39 081 7723344; e-mail address: delliveneri@portici.enea.it 118KB
04/06/2004 0.00.00 SHADING EFFECT ON MPPT PERFORMANCE IN A GRID CONNECTED 20 kWp PV SYSTEM Within the Italian PV roof-top Programme, a 20 kWp generator has been installed in Torino on the façade of the company for the management of waste materials (AMIAT). Due to the façade azimuth (20° W) besides the distances among the floors, a partial shading effect occurs during morning periods from April to September. The shading effect determines an important decrease of the module available power. However the paper focuses on the MPPT performance of inverters, in the mentioned shading conditions, during which experimental data have been recorded. Due to the tracking algorithm, the MPPT efficiency decreases (also < 80%) and the DC signals have ripple with greater amplitude but frequency lower than the typical 100 Hz value. These increased ripples (≈30%) produce an overload operation for the capacitors and inductor of the DC-DC converter that performs the tracking. This repetitive condition can cause failure of the inverters. Keywords: 1 Shading , 2 Tracking , 3 Inverter Pubblicazioni/2004/Parigi5BV122.pdf G. Graditi (1,2), F Spertino (3), S. Li Causi (4) (1) ENEA - C.R. Portici - Napoli; Via Vecchio Macello - 80055 Portici, Napoli, Italy Tel: +39081-7723400; Fax: +39081-7723344 - Email: giorgio.graditi@portici.enea.it (2) Università di Palermo - Dipartimento di Ingegneria Elettrica Viale delle Scienze - 90128 Palermo, Italy Tel.+390916615221; Fax+39091488452; Email: graditi@diepa.unipa.it (3) Politecnico di Torino - Dipartimento di Ingegneria Elettrica - Corso Duca degli Abruzzi 24 - 10129 Torino, Italy Tel: +39011-5647105; fax +39011-5647199 - Email: filippo.spertino@polito.it (4) ENEA - C. R. Casaccia - Roma - Via Anguillarese 301 - 00060 S. M. di Galeria, Roma, Italy Tel: +390630484110; fax: +390630484643 - Email: licausi@casaccia.enea.it 612KB
04/06/2004 0.00.00 A GLOBAL APPROACH FOR MEASURING THE CONCENTRATING PV CELLS In the lack of a specific standard for concentrating cells I-V characterization and with the need to test the electrical performance of about 7500 cells, we adopted a global approach strategy by making measurements under different test conditions. We hoped that the understanding of the limitations for each methodology and the comparisons of the results would have given some indications about the righteousness and accuracy of the measurements and, once the proper technique were been set up, also information on the quality of the cells. So a continuous solar simulator for cells and a flash solar simulator for large area PV modules, e.g. at one sun, were considered; the required irradiance level was then reached either by drawing the test plane nearer to the lamp, accordingly to the minus square distance law, or by using optics along the light path to focus on the receiver. The comparison between the measurements showed slight variations, especially in terms of fill factor and efficiencies. The paper tries to give an understanding of the different results and at the same time an indication of the pros and cons of each methodology. We hope that this could be also useful for the in progress preparation of the standard. Keywords: Concentrator cells, characterization Pubblicazioni/2004/Parigi5BV215.pdf M. Pellegrino, S. Bolognesi, G.Flaminio, C. Privato, A. Romano and A. Sarno ENEA Centro Ricerche Portici Località Granatello. P.O. Box 32,I-80055 Portici (NA), Italy. tel:+39-81-7723-267, Fax:+39-81-7723-344 519KB
04/06/2004 0.00.00 THE SKY INTO A ROOM The integration of photovoltaics in the urban scale has become one of the most interesting sectors for solar applications and one of the added functions of the Building Integrated Photovoltaics is the light control use either as a day lighting device or as a sun screen. For that kind of application glass-glass semitransparent modules can be used to shed a proper light inside a room. Daylight is one of the most interesting aspect of the building architectural project, not only for the saving of electric power, but also for the visual comfort and generally for the health effects on human being. Medical surveys showed that the day lighting gives a good attitude for people inside a confined room letting them to feel in more harmony with the outside environment. The quality and the quantity of the natural light should be carefully controlled in a good light project according to the final destination of the room. Other inconvenient problems like the excessive glare, usually in wintertime, and the overheating of the room in summertime must be addressed. According to some rules 200 lx is the suggested minimum value for not demanding working rooms, while 20 lx could be acceptable for transit zones. Keywords: Façade, module integration, optical properties Pubblicazioni/2004/Parigi6DV230.pdf M. Pellegrino, S. Bolognesi, L. Bonfili* , F. Fantozzi*, G.Flaminio and C. Privato) ENEA Centro Ricerche Portici Località Granatello. P.O. Box 32,I-80055 Portici (NA), Italy. tel:+39-81-7723-267, Fax:+39-81-7723-344 * Ingegneria Dipartimento di Energia Pisa, Italy 499KB
04/06/2004 0.00.00 DETERMINATION OF THE THERMAL PROPERTIES OF PV COMPONENT IN BUILDINGS The data on thermal exchange properties of materials and structures applied on buildings are important for compliance to defined standard, specially for the certification of the building elements and the European Union has recently issued the directive 2002/91/CE about the energetic efficiency of the building stating the energetic certification compulsory. This should be also valid for the Building Integrated Photovoltaics used for the for thermal insulation. The working temperature and the thermal conductance (or conductivity) are required for a proper installation of modules. For the temperature measurements the infrared thermal camera, traditionally used for the hot spot test, is useful for monitoring and mapping the envelope temperatures. The thermal exchange properties depend on the sample, its size, the operating conditions, the air flow, the humidity and so on. So the test should be made with a good control of all those parameters and there are two complementary approaches for performing the test, one is by means of the guarded hot box and the other is by means of the Calibrated Hot Box. For the panel conductance characterization we first considered the standards for materials normally used in façade, and adapted them for the PV case. Keywords: Thermal performance, qualification and testing, building integration, Pubblicazioni/2004/Parigi6DV231.pdf M. Pellegrino, S. Bolognesi, L. Bonfili* , F. Fantozzi*, G.Flaminio and C. Privato ENEA Centro Ricerche Portici Località Granatello. P.O. Box 32,I-80055 Portici (NA), Italy. tel:+39-81-7723-267, Fax:+39-81-7723-344 *Università degli Studi di Pisa FAC. di INGEGNERIA - via Diotisalvi,2 56126 PISA 734KB
14/04/2004 0.00.00 A Study for Optimizing the Management Strategies of a Hybrid Photovoltaic-Diesel Power Generation System Abstract. In this paper the Authors, on the basis of a software for the management of the hybrid systems, optimize the performance of a real plant under different working conditions. The plant under examination is called Delphos and is a solar installation of ENEA (National Agency of Alternative Energy) in the South of Italy. Key words: hybrid systems, optimization Pubblicazioni/2004/Spagna.pdf M. Sylos Labini1, G. Delvecchio2, M. Guerra3, C. Lofrumento1 and F. Neri1 1 Department of Electrotechnics and Electronics - Polytechnic of Bari Via E. Orabona 4 - 70125 Bari (Italy) phone: +39 080 5963256, fax: +39 080 5963410, e-mail: sylos@poliba.it 2 Technical Area - University of Bari Piazza Umberto I n.1 , 70100 Bari (Italy) phone:+39 080 5714648, fax:+39 080 5714655, e-mail: g.delvecchio@area-tecnica.uniba.it 3 ENEA – Experimental Area Monte Aquilone SS 89 km 178+700, 71043 Manfredonia FG (Italy) phone: +39 0884 543493, fax: +39 0884 543940, e-mail: michele.guerra@portici.enea.it 435KB
14/04/2004 0.00.00 A Study for Optimizing the Management Strategies of a Hybrid Photovoltaic-Diesel Power Generation System In this paper the Authors, on the basis of a software for the management of the hybrid systems, optimize the performance of a real plant under different working conditions. The plant under examination is called Delphos and is a solar installation of ENEA (National Agency of Alternative Energy) in the South of Italy. Key words: hybrid systems, optimization, Pubblicazioni/2004/Spagna.pdf M. Sylos Labini1, G. Delvecchio2, M. Guerra3, C. Lofrumento1 and F. Neri1 1 Department of Electrotechnics and Electronics - Polytechnic of Bari Via E. Orabona 4 - 70125 Bari (Italy) phone: +39 080 5963256, fax: +39 080 5963410, e-mail: sylos@poliba.it 2 Technical Area - University of Bari Piazza Umberto I n.1 , 70100 Bari (Italy) phone:+39 080 5714648, fax:+39 080 5714655, e-mail: g.delvecchio@area-tecnica.uniba.it 3 ENEA – Experimental Area Monte Aquilone SS 89 km 178+700, 71043 Manfredonia FG (Italy) phone: +39 0884 543493, fax: +39 0884 543940, e-mail: michele.guerra@portici.enea.it 434KB
02/04/2004 0.00.00 Testing of an Innovative Small Size Hybrid PV-Fuel Generator An innovative small size hybrid photovoltaic-electrical fuel generator was planned and realized in the ENEA Monte Aquilone Test Site, located in the South of Italy, near Manfredonia (Apulia, Italy). This generator utilizes an innovative equipment, a modular battery inverter Sunny Island made by SMA, provided with a bi-directional converter to charge and discharge the batteries and with a new electronic switch that defines the current operating mode: - in current-controlled operation mode, the converter is synchronized to an external power supply unit, that can be a public grid or an electrical generator; - in voltage-controlled operation mode, the converter supports and controls an optimal voltage at industrial frequency. The Sunny Island is an equipment capable to control the battery loading and at the same time to optimise the voltage and frequency of the bus AC on which different electrical loads and Energy systems are connected. A simple single-phase power supply can be arranged with one single Sunny Island and a standard battery pack. The energy systems can be selected between several generators depending on availability: photovoltaic plants, small wind plants and fuel units. The goal of this project is to demonstrate that the use of bidirectional converter allows to reduce the size and the cost of a PV system for island application and, at the same time, to enhance the reliability of the produced electrical power by using an additional back up electrical fuel generator. In order to make a comparison of the management and realization costs among several systems, the sizing of components was determined in the different cases: classic PV system and hybrid with electrical fuel generator. The experimental activity consists in the data acquisition and analysis of the system working in real conditions. First results confirm the planning which promised a cost reduction of the produced electrical kWh. Pubblicazioni/2004/FriburgTestingInnovativeHPV-FuelGenerat.pdf N. Giancaspro*(1); C. Privato** *ENEA Area Sperimentale Monte Aquilone, S.S. Garganica 89, km 178+700; 71043 Manfredonia (FG), Italy **ENEA R.C. Portici, Loc. Granatello; 80055 Portici (NA), Italy (1)corresponding author: tel +39 0884 543493; e-mail giancaspro@portici.enea.it 1.1Mb
02/04/2004 0.00.00 PROGRESS ON PV MODULE PROCESSING BASED ON SILICON HETEROSTRUCTURES - MOPHET We report the progress to date of the MOPHET project, partly funded by the European Commission in the V Framework Programme. The project aims to develop a technology which matches an all screen printing automated process for the production of PV modules, with high efficiency – low thermal budget devices. This allows employing thin film heterostructures such as μc-Si/c-Si, a-Si/c-Si, TCO/c-Si which can reach high efficiency values, and can be scaled up to manufacturing levels [1]. The possibility of replacing the traditional p-type with n-type silicon substrates is explored, in order to eliminate degradation effects due to B-O pairs. Results up to date include the realisation of lab scale high efficiency cells, the realisation of mini-modules using heterostructure cells and the all-screen printed approach, and the realisation of small quantities of high quality n-type multicrystalline and EFG ribbon silicon substrates. Keywords: PV Module - 1: Cost Reduction - 2: Heterojunction - 3 Pubblicazioni/2004/Parigi2DO26.pdf A. D’Andrea 6 I-00048 Nettuno, Italy Tel +390698560403, E-mail francesca.ferrazza@enitecnologie.eni.it W. Schmidt, H. v. Campe, A. Seidl RWE Schott Solar GmbH, Alzenau, Germany J. Cárabe and J.J. Gandía CIEMAT, Madrid, Spain F. Roca, M. Tucci, E. Bobeico ENEA Portici Research Centre, Italy A. Björseth , E. Sauar ScanWafer AS, Glomfjord,Norway J.E. Cotter , J.H.Guo Centre for Photovoltaic Engineering, the University of New South Wales, Sydney 2052, New South Wales, Australia 1.48Mb
01/04/2004 0.00.00 The Lighting Project By Means Of Photovoltaic Daylight Factor The use of the sun light for the lighting of confined rooms has been not only increased but even recommended for different reasons, economic for the savings of the energy bill and technical for the increasing the comfort by using a natural light source with characteristics better for the people. Contemporary the Building Integration of Photovoltaics has gradually increased due also to more favourable subsidies and the modules could be used for daylighting as sunscreen or sun curtain. The integration in buildings of semitransparent or translucent modules calls for the determination of the optical transmittance in order to get the daylight factor and so to determine the quantity of light entering through the component inside the room. The paper shows two approaches: the first one has been used to verify a project already realized in order to control its capability to the use and the other is during the project phase. We followed both the approaches for the evaluation of the comfort gain for a project realized in our centre where the south face of 11.7 m² of a little room previously covered of glasses was replaced by means of PV modules. Incidentally these modules were designed also for high standard architecture and were aesthetically interesting. Since the daylight factor contains the transmittance of the component, the determination of the transmittance modules was determined. The daylight factor was measured at different points both at the floor level and at the working plane, about 1 m, according to the standard. The procedure was made before and after the installation of the PV façade. The measurements revealed that: the average daylight factor was reduced from 18 % to 9 %, so the solar contribution to the room illumination is not compromised, but at the same time both the glaring effects and the summertime thermal overheating are largely reduced, making the room more comfortable. The methodology was applied in two cases: one checking the optical gain after a PV plant was installed at a façade and the other one on a project for a restructuring of a building. Pubblicazioni/2004/FriburgoDaylight.pdf.pdf Michele Pellegrino, S. Bolognesi,L. Bonfili*, G. Flaminio and C. Privato ENEA Centro Ricerche, Località Granatello. P.O. Box 32,I-80055 Portici (NA), Italy. tel:+39-81-7723-267, Fax:+39-81-7723-344; mail to Michele.pellegrino@portici.enea.it *thesist at ENEA 1,5MB
01/04/2004 0.00.00 ELECTROMAGNETIC COMPATIBILITY FOR THE BIPV PV plants could be the cause of radio frequency (RF) conducted radiated emissions, namely electromagnetic signals, at both the levels of voltage and current, travelling along the electric cables. The problem can be even more relevant for the Building Integrated PhotoVoltaics BIPV applications since their closeness to the domestic activities; preliminary measurements have been carried out for pre-compliance purpose at the Research Centre ENEA on a small photovoltaic façade, while the plant was being in operation, e.g. delivering power. The pre-compliance procedure is vey important since if the conducted radiations overcame the standard values the same levels of signals could likely be present in other parts of the electric circuit inside the building, giving unwilling interferences with the other connected appliances. Another kind of noise could generate because the size of the modules and the length of the connection cables could make the plant acting as receiving antenna, so capturing and then introducing foreigner RF electromagnetic signals inside the buildings, mainly local broadcasting radio stations. In our survey the effects of differently configured inverters have been analysed: in one case one by one module connected inverters and the more traditional single inverter for a module string, in the other. Pubblicazioni/2004/FriburgoEmc.pdf.pdf Michele Pellegrino, A. Matano, C. Privato and R.Schioppo * ENEA Centro Ricerche, Località Granatello. P.O. Box 32,I-80055 Portici (NA), Italy. tel:+39-81-7723-267, Fax:+39-81-7723-344; mail to Michele.pellegrino@portici.enea.it *ENEA Centro Ricerche Area Sperimentale di Monteaquilone (FG), Italy 101KB
09/02/2004 0.00.00 PLASTICS STRUCTURED OPTICS FOR SOLAR CONCENTRATING IN PV SYSTEMS ENEA launched the Point Focus PhoCUS (Photovoltaic Concentrators to Utility Scale) Project in order to investigate the photovoltaic concentrators technologies and to assess the technical and economical feasibility of this application in Italy for electrical energy generation and two main targets in terms of efficiency and economical aspects, a cost per kWp less than 2 € and a generation cost less than 0.10 € per kWh, were set. The injection process was selected among all the moulding technologies since its large throughput and the very low unit cost makes it preferable for industrial transfer and market accessibility; but since the aspect ratios and the quality of the molded parts have resulted sometimes not being very satisfactory, we decided to begin a research on the molding injection technology aimed to optimize the process in order to have a material as good and cheap as possible. As material, among different high optical quality plastics, the polymethylmethacrilate, PMMA, was also considered for the manufacturing due to its superior optical characteristics/convenience ratio. Pubblicazioni/2004/Parigi 5BV.2.16.pdf Michele Pellegrino, Carlo Privato and Angelo Sarno *Antonio Apicella and Raffaella Aversa ENEA Centro Ricerche, Località Granatello. Portici (NA), *DISPAMA, Seconda Università di Napoli, Aversa (NA) 1.24MB
04/11/2003 0.00.00 VHF PECVD MICROCRYSTALLINE SILICON: FROM MATERIAL TO SOLAR CELLS Intrinsic microcrystalline silicon has been deposited by very high frequency plasma enhanced chemical vapor deposition technique at two different frequencies, 90 and 100 MHz. Different gas mixtures of silane and hydrogen were utilized, while keeping the substrate temperature at 220°C and the chamber pressure at 950 mTorr. In particular, the effect of plasma power has been investigated at both frequencies in the range 20 – 40 W. The material was characterized in terms of structural, electrical and optical properties. The optimised material was inserted in p-i-n solar cells. Since the properties of thin p-layers (~ 200 Å) strongly affect the solar cell performance, a particular care was directed to the structural and electrical characterization of this material. Preliminary results on the devices are presented: efficiency of about 3.8 % was reached for 1 μm thick solar cells. Keywords: thin film silicon; microcrystalline silicon; solar cells; VHF PECVD. Pubblicazioni/2003/EMRSDelliveneri.pdf P. Delli Veneri, L. V. Mercaldo∗, C. Minarini, C. Privato 732KB
03/11/2003 0.00.00 A PROJECT FOR AN ENERGY MUSEUM AT THE FOOT OF DELPHOS PV PLANT A project for a solar building at the foot of Delphos (a demonstrative electrical PV system located in the South of Italy realized by ENEA in the 80’s) is at the moment worked out by ENEA together with MCA. Many people every year visit the site of Delphos; moreover by an architectonic point of view this PV plant has a particularity in its visual aspect: in fact, it was realized in one piece only, looking something like a photovoltaic shape in the ground, or like a pitch, and so it has a natural architectural vocation, and a special relation with the landscape. It is intention of ENEA the realization of a new demonstrative and experimental Energy Museum that should be like a manifesto for the solar architecture; the aim of the project is to exploit the possibilities of the site both in terms of dissemination and scientific experimentation. A preliminary project has been developed; according to this project the building physically integrates the pitch of Delphos such as the landscape, it is an active envelope conceived in terms of awareness of the energetic processes, and with the utilization of photovoltaic innovative components and advanced strategies of microclimatic control. The building is articulated in different functions including a visitors centre and some research offices, so we can examine different themes connected to the different functions; particularly: daylighting in the offices, natural ventilation in the educational zone, and architectural integration of photovoltaic systems in the expo zone. In order to predict the thermal and energetic behaviour of the building and to verify the microclimate strategies we use a commercial tools, the TRNSYS. Pubblicazioni/2003/GoteborgScognamiglio.pdf M. Citterio(1); MCA Mario Cucinella Architects(2); C. Privato(3) and A. Scognamiglio(3) (1)ENEA R.C. Casaccia, via Anguillarese, 301; 00060 S. Maria di Galeria (Rome), Italy (2)MCA Mario Cucinella Architects, via G. Matteotti, 21; 40129 Bologna, Italy (3)ENEA R.C. Portici, Loc. Granatello; 80055 Portici (Naples), Italy Phone: +39 081 7723304; fax: +39 081 7723344; mail to: alessandra.scognamiglio@portici.enea.it 546KB
02/11/2003 0.00.00 DO YOU KNOW? I AM A BUILDING SKIN WORKING Employment of Photovoltaics on buildings has recently grown up in a very surprising way throughout all the world. Among different reasons, both technical and economical, there could be just another explanation that relies on a someway new concept of buildings: following this approach they are considered not only boxes devoted to keep the human activities inside, but their walls are perceived as active elements that interact significantly with the outside environment and the inside as well. In that case the building skin plays an active role and positively contribute to the improving of the building general performance. The photovoltaic modules can do that in such a silent, relentless and reliable way that one becomes even unaware of having them working at all. The drawback is that from an electrical point of view the modules exposure to the sun can not always be optimized in terms of the right tilt and azimuth angles and drops from the rated power values are to be expected. But in these cases how much of the maximum possible power can be allowed to be sacrificed and is this choice worth of that? The paper will show some preliminary results of the tests undertaken on different kinds of structural PV components, specifically designed to be integrated in the façade, in order to investigate their performance flexibility at different illumination conditions, both natural and artificial, and at various, not optimal, geometric exposures. Pubblicazioni/2003/GoteborgPellegrino.pdf Michele Pellegrino, Giovanni Flaminio, Carlo Privato and Alessandra Scognamiglio 650KB
27/10/2003 0.00.00 IMPIANTI FOTOVOLTAICI: aspetti normativi Pubblicazioni/2003/AEINormativa.pdf Giorgio Graditi, Felice Apicella, Centro Ric. ENEA Portici - Napoli Vincenzo Cataliotti Università degli Studi di Palermo 732KB
14/10/2003 0.00.00 Camera for recording light backscattered from textured photovoltaic samples A camera for recording the intensity of light backscattered from textured photovoltaic (PV) samples is described. It was realized by modifying a professional folding camera, for use on an optical bench. The collimated light from a laser source crosses the camera and impinges on the test sample. The light backscattered by the sample exposes a punched photographic plate placed on the front side of the camera. With a proper choice of laser light intensity and wavelength, the optical diffusing effects produced by surface morphology or by subsurface features of the sample can be recorded in this way. The analysis of light diffusing characteristics of textured PV samples, mainly based on crystalline silicon material, can be directed towards improving their light collection capabilities. The camera can be assembled in such a way as to record the light diffusion images produced in reflection by both small and large samples, or those produced in transmission from textured semitransparent materials. Keywords: Light scattering, recording, textured silicon, photovoltaic devices Pubblicazioni/2003/JournalOpticsParretta.pdf Antonio Parretta 1.1MB
14/10/2003 0.00.00 Investigation of minority carrier diffusion length in shallow junctions by angle-resolved illumination technique In this paper, we discuss a new approach to the determination of minority carrier diffusion length (Ld) on flat top surface shallow junction devices in which photocurrent is dominated by diffusion component as in solar cells. In our method, we propose the use of a single monochromatic light beam of appropriate wavelength, incident on the device surface at various angles. Under such experimental conditions, the short circuit current of the device is expressed as a function of the internal spectral response and device reflectance. Then diffusion length can be simply derived by the analysis of the experimental ratio between photocurrent measured at various incidence angles and when light impinges the device orthogonally, as function of the incident angle. An analytical model is proposed based on the modified absorption coefficient as a function of refractive angle and an experimental set-up for the evaluation of minority carrier diffusion length is proposed. # 2003 Elsevier B.V. All rights reserved. Keywords: Diffusion length; Solar cell; Integrating sphere Pubblicazioni/2003/MaterialScienceEngineeringParretta.pdf A. Parretta *, P. Grillo, M. Tucci 368KB
14/05/2003 0.00.00 SISTEMI FOTOVOLTAICI e gruppi statici di CONTINUITÀ LÕintegrazione della generazione fotovoltaica nei gruppi statici di continuità permette di abbinare i vantaggi dellÕuso di una fonte rinnovabile alla fornitura di un servizio elettrico con elevati standard qualitativi. Pubblicazioni/2003/AEIPV_UPS.pdf Giorgio Graditi Felice Apicella Centro Ricerche ENEA, Portici Vincenzo Cataliotti Università degli Studi di Palermo 785KB
14/05/2003 0.00.00 Convertitori statici di potenza negli impianti fotovoltaici Pubblicazioni/2003/UTETInverter.pdf Giorgio Graditi, Felice Apicella 5.8MB
09/02/2003 0.00.00 THE STATUS OF THE PhoCUS PROJECT: PRELIMINARY RESULTS The main purpose of the PhoCUS (Photovoltaic Concentrators to Utility Scale) project is to develop a photovoltaic concentrators technology ( PV C-technology) in order to demonstrate the technical feasibility of this application in Italy and to assess its greater potentials to drive a reduction of the PV System investment cost. The road-map of the project was outlined on the basis of a detailed feasibility study aimed at identifying the most promising technologies to get in medium term a system cost of 4.1€/Wp with a production of 5MW/year. The first phase of the project, lasting three years (2002-2004) is mainly focused on Research&Development and Demonstration activities addressed respectivily to develop and optimise the most appropriate technologies for the solar cell, the optical device, the module, and the solar tracker and to design and install a 5 kW standard unit. A pilot demonstrative plant (25 kW) consisting of 5 standard units will be installed at Enea Monte Aquilone Test-Site, located in Manfredonia (South East of Italy) for field testing both the single components and the whole system. In the frame of the project scientific collaborations with National Universities and Research Institutions have been started as well as two qualified industrial operators, namely Eurosolare and Galileo Avionica, are cooperating in industrial design and realizing the prototypes of the C-module and the tracking structure. The realization of the single components, like the solar cell assembling and the optical devices, is benefiting by a fruitful interation with International and National operators. This paper will report the status of the differet activities ongoing and present and discuss the results so far achieved. Keywords: concentrators, supporting structure, PV module. Pubblicazioni/2003/PhocusAustralia.pdf A. Sarno*, F. Apicella, L. Pirozzi, M.Pellegrino, C.Privato, F.Roca Enea Portici Research Center Loc.Granatello 80055 Portici (Napoli) - Italy Enea Casaccia Research Center Via Anguillarese 301 00060 Roma – Italy * phone +39 081 77 23 202 e-mail: sarno@ portici.enea.it 311KB
03/02/2003 0.00.00 Analysis of microcrystalline silicon absorber layer in solar cell devices Microcrystalline silicon thin film solar cells has been prepared using intrinsic layer deposited by very high frequency PECVD at 100 MHz. Different gas mixtures of silane and hydrogen have been utilized, while keeping the substrate temperature at 220 °C and the chamber pressure at 950 mTorr. The effects of both plasma power and thickness of active layer were investigated with the aid of a numerical model able to describe stacked structure of semiconductor thin film. A good agreement with experimental data has been found by suitably choosing the thickness and defect density of these layers. The effect of hydrogen dilution, plasma power and active layer thichness has been investigated. Pubblicazioni/2003/icams.pdf P. delli Veneri, L.V. Mercaldo, M. Tucci 272KB
16/11/2002 0.00.00 MONITORING OF INTERFACE DEFECTS IN a-Si:H/c-Si HETEROJUNCTION SOLAR CELLS In this paper we analyzed amorphous crystalline silicon heterostructure for photovoltaic application. In particular we investigated the difference and the potentiality of the two kind of heterojunctions: p-type amorphous silicon / n type crystalline silicon; n-type amorphous silicon / p-type crystalline silicon. With the aid of a numerical model able to solve AC and DC problem in multiplayer structure we evaluated the transport mechanism and the defect behavior at the junction for both kind of solar cell devices. Difference in the technological steps needed to heterostructure formation have been considered for high efficiency solar cell. Finally an explanation of the difference in the role played by the defect density at the heterojunction for both kind of structure has been proposed. Keywords: 1 – heterostructure; 2 – solar cell; 3 – defect. Pubblicazioni/2002/RomaV115.pdf Mario Tucci, Francesco Roca, Giampiero de Cesare*, Fabrizio Palma* ENEA Research Center, Località Granatello, Portici, 80055 Napoli Italy *Electronic Engineering, University of Rome “La Sapienza”, via Eudossiana 18, I-00184 Roma, Italy, 157KB
16/11/2002 0.00.00 Optical characterization of recombination parameters of bulk silicon and crystalline/amorphous silicon interface in solar cells The knowledge of silicon recombination parameters is of paramount importance in solar cells manufacturing processes because they are strictly related to the final achievable efficiency. The present work is aimed to the characterization of crystalline/amorphous silicon interfaces by means of an optical contactless technique. In particular, we used a pump-probe measurement apparatus based on the use of a modulated laser beam (pump beam, λ=0.80µm) to inject charge carriers in the solar cell and a CW pigtailed laser diode (probe beam, λ=1.55µm) to monitor the recombination process. Through the measurement of the sample frequency response it is possible to separate the bulk recombination lifetime and the surface recombination velocities by means of suitable fitting routines. Different heterojunction solar cells have been analyzed by means of the above method. Pubblicazioni/2002/RomaV136.pdf R. Bernini*, S. Campopiano**, N. Martucciello§, F. Roca§, L. Zeni** M. Losurdo+, G. Bruno+ *CNR-IREA Via Diocleziano 328 – 80124 Napoli (Italy) **Seconda Università di Napoli Dipartimento di Ingegneria dell’Informazione Via Roma 29, 81031 Aversa (Italy) §Centro Ricerche ENEA Località Granatello, Portici - Napoli (Italy) +CNR-IMIP Via Orabona 4 - 70126 Bari (Italy). 263KB
13/11/2002 0.00.00 THE PhoCUS PROJECT The PhoCUS (Photovoltaic Concentrators to Utility Scale) Project started in the late 2001 in order to investigate the photovoltaic concentrators technologies and to assess the technical and economical feasibility of this application in Italy for electrical energy generation. The first phase of the project, lasting three years, is focused on Research, Development and Demonstration activities starting with the development and the optimisation of the most appropriate technologies for the solar cell, the optical device and the module, as well as to the best design of the BOS (Balance Of System) components with particular attention to the solar tracker. Concerning the demonstration and testing aspects, it is expected that a standard unit (5kW) will be developed by Enea in cooperation with national operators; a pilot plant (25 kW) consisting of 5 standard units will be installed in the Enea Monte Aquilone Test-Site, located in Manfredonia (South East of Italy). The PV generators of the first standard units will be composed of modules realized by arranging commercial backside-contact c-Si cells by Sunpower Corporation, optimised to a concentration ratio from 100 to 400X. The status of the project as well as the preliminary technical results will be presented and discussed. Keywords: concentrators, supporting structure, PV module. Pubblicazioni/2002/RomaPhoCUS.pdf A.Sarno**, G.Contento, A.Mittiga*, C.Privato, F.Roca Enea Portici Research Center Loc.Granatello 80055 Portici (Napoli) - Italy *Enea Casaccia Research Center Via Anguillarese 301 00060 Roma – Italy ** phone +39 081 77 23 202 e-mail: sarno@ portici.enea.it 437KB
04/11/2002 0.00.00 MINORITY CARRIER DIFFUSION LENGTH MEASUREMENTS IN c-SI HOMOJUNCTIONS BY ANGLE-RESOLVED ILLUMINATION TECHNIQUE In this paper we present a new approach to the determination of minority carrier diffusion length on flat top surface shallow junction devices in which photocurrent is dominated by diffusion component, as in solar cells. In our method we propose the use of a single monochromatic light beam, of appropriate wavelength, incident on the device surface at various angles. Under such experimental conditions, the short-circuit current of the device is expressed as a function of the internal spectral response and device reflectance. Then diffusion length can be simply derived by the analysis of the experimental ratio between photocurrent measured at various incidence angles and photocurrent measured when light impinges the device orthogonally, as function of the incident angle. An analytical model is proposed, based on the modified absorption coefficient as a function of refractive angle, and an experimental set-up for the evaluation of minority carrier diffusion length is proposed. Keywords: diffusion length, solar cell, integrating sphere. Pubblicazioni/2002/RomaV118.pdf Antonio Parretta, Mario Tucci, Pietro Grillo, Pasquale Maddalena* ENEA Centro Ricerche Portici, 80055 Portici (Na), Italy *INFM, Dip. Scienze Fisiche, Università Federico II, 80126 Napoli, Italy 129KB
04/11/2002 0.00.00 AESTHETICAL APPEAL OF BIPV OR ELECTRICAL PERFORMANCE One of the key of success for the building integration of PV seems to lie on the aesthetical aspect of the PV modules. The quality image issue is not so trivial since they are just the end users that need to be convinced to accept the installation and in any case the modules have to be integrated into the overall concept within the building design. But in these cases how much of the maximum possible power can be allowed to be sacrificed for aesthetics sake and is this choice worth of that? The paper will show some preliminary results on different kinds of structural PV components specifically designed to be integrated in the façade, since in this case the aesthetical aspects vs. the electrical performances are more important. Modules specifically designed to fulfill high architectural visual standards were tested in order to investigate their performance flexibility at different illumination conditions and at various, not optimal, geometric exposures. The general behavior was evaluated under both an architectural and an engineering point of view. Keywords: building, characterization, evaluation Pubblicazioni/2002/RomaV825.pdf Michele Pellegrino, G. Flaminio, G. Leanza, C. Privato and A. Scognamiglio ENEA Centro Ricerche, Località Granatello. P.O. Box 32,I-80055 Portici (NA), Italy. tel:+39-81-7723-267, Fax:+39-81-7723-344; mail to pellegrino@portici.enea.it 424KB
24/10/2002 0.00.00 NEW R&D TRENDS IN EUROPE ON THIN-SILICON PHOTOVOLTAICS About 99% of the solar-cell world production for PV terrestrial applications is dominated by silicon, of whose share, about 80% corresponds to wafer technology. Experience has induced the conviction that silicon technology must keep this predominant position for the next 10 years. Progress in wafer technology is needed in the direction of increasing production and lowering costs of feedstock, mainly by investigating new growth processes leading to a cheaper silicon of an acceptable quality. The development of medium-thickness polycrystalline ribbon silicon and similar silicon-based materials is in the forefront of photovoltaic R&D. In parallel, the efforts on thin-film silicon technology must be concentrated on enhancing material quality by improving film crystallinity and simultaneously thickness and growth rate. New approaches for the preparation of silicon impose a convergence of two research lines traditionally separated. The European state of the art in thin silicon for PV is analysed and described. A successful European RTD strategy imposes the collaboration of public and private institutions both within the present Framework Programme, FP5, and even more in the coming FP6, by means of Networks of Excellence (NoE) and Integrated projects (IP) in order to create the so called European Research Area (ERA). Keywords: Silicon-1: Thin Solar cells-2: Heterojunction-3. Pubblicazioni/2002/RomaOE24.pdf F. Roca1 & J. Cárabe2 1ENEA Portici Research Centre – Località Granatello-80055 Portici (Naples) Italy. Tel: +39081 7723 270; fax:+39081-7723344; e-mail:roca@portici.enea.it 2CIEMAT DER – Avda. Complutense, 22 E-28040 Madrid. Spain Tel: +34.913466047; fax: +34.913466037; e-mail: julio.carabe@ciemat.es 161KB
18/10/2002 0.00.00 OPTICAL DEGRADATION OF PHOTOVOLTAIC MODULES The investigation of degradation effects produced on single-Si and multi-Si photovoltaic modules after 15 years of outdoor operation was carried out by comparing the optical reflectance of exposed modules with that of original, unexposed counterparts. The photovoltaic modules refer to four different fabrication technologies and belong to the 1st Section of Delphos large-scale ENEA PV plant located in Manfredonia (South of Italy). The corresponding PV generators had shown an electrical degradation of 11–22% on output power and 9–14% on output current, depending on the fabrication technology. The effects of ageing on the dismounted and cleaned modules appear as an evident discolouration of the ARC layer or as formation of halos over the cell surface, and was investigated by total integrated reflectance measurements under diffuse light and spectral reflectance measurements (300-1100 nm interval) under direct light. Two specific apparatus, both equipped with 40-cm diameter integrating spheres, were used. The exposed modules show an increase of reflectance under diffuse light, ~1% for single-Si cells and ~2% for multi-Si cells, with respect to the unexposed ones. Also the spectral measurements show an increase of reflectance, except for cells with ARC where a clear decrease in the blue region (400–500 nm) is observed. The effect of degradation is to level the reflectance spectrum. Keywords: PV Module, single-Si, Degradation, Optical Properties Pubblicazioni/2002/RomaOD92.pdf A. Parretta*1, G. Graditi1, M. Guerra2, R. Schioppo2, P. Maddalena3, E. Massera3 1ENEA Centro Ricerche Portici, Località Granatello, 80055 Portici (Na), Italy 2ENEA Area Sperimentale di Monte Aquilone, Manfredonia (FG), Italy 3Dip. Scienze Fisiche, Compl. Universitario Monte S. Angelo, Via Cintia, 80126 Napoli, Italy *1Corresponding author. Phone: +39 (0)81 7723262; Fax: +39 (0)81 7723344: E-mail: parretta@portici.enea.it 1.58MB
17/10/2002 0.00.00 TRANSPARENT p-TYPE CONDUCTING SrCu2O2 FILMS FOR INNOVATIVE PHOTOVOLTAIC DEVICES Transparent conductive oxides (TCO) catalysed relevant interest in photovoltaics thanks to the high electrical conductivity coupled to optical transparency in the visible portion of the spectrum. On the other hand the materials used at present are based on n-type conductivity (Indium Tin Oxide-ITO, Zinc Oxide-ZnO, Tin Oxide-SnO2). Aim of this work is the low temperature deposition of p-type TCO. Thin films of copper-strontium mixed oxide have been deposited on glass and quartz substrates varying the substrate temperature and oxygen partial pressure by using deposition techniques very diffused in PV labs. For the first time, polycrystalline films of SrCu2O2 were obtained using e-beam evaporation in O2 atmosphere at relatively low temperature (350 °C) with transparency of over 60 % in the visible light range and a high optical transmittance in near-infrared region. The optical band gap of thin film was estimated to be ~ 3.12eV. Seebeck and Hall effects measurements confirmed the p-type nature of semiconductors and a conductivity as high as 5.3x10-2 S/cm for non intentionally doped materials was measured. Hole concentration and mobility at room temperature were 1.5x1017 cm-3 and 2.2 cm2V-1s-1, respectively. X-ray diffraction measurements revealed a polycrystalline structure of the films. Keywords: p-type TCO (Transparent Conducting Oxides), thin films, e-beam evaporation Pubblicazioni/2002/RomaOC33.pdf E. Bobeico2, F.Varsano1, C.Minarini1, F.Roca1 1ENEA Centro Ricerche Portici, Località Granatello, 80055 Portici (Na), Italy 2Institute of Applied Physics, Academiei str.5, Chisinau, MD-2028, Republic of Moldova phone: +39 0817723 203; fax: +39 0817723 344; e-mail: bobeico_eugenia@mail.ru 160KB
16/10/2002 0.00.00 FIELD EFFECT a-Si:H SOLAR CELLS In this paper we present a first realization of a Field Effect solar cell, based on the top channel configuration. The amorphous silicon p-i-n structure was deposited by PECVD on metal and TCO substrates. Thin film metal contact were conformed by photo-lithographic process. Reactive ion etching of the superficial n layer, in the area not covered by the contacts, was performed to expose the intrinsic layer. PECVD silicon nitride was deposited for passivation, finally transparent conductive oxide was deposited to form the top gate electrode. Results showing the field effect enhancement of photocarrier collection will be presented, together with characterization of silicon nitride passivation layer under high carrier density in the field effect channel. Keywords: a-Si, Inversion-layer, Silicon Nitride. Pubblicazioni/2002/RomaOC12.pdf D. Caputo (1), G. De Cesare(1), F. Palma(1), G. Nobile(2), M. Tucci(2) (1) INFM Unita’ di Roma and Dipartimento di Ingegneria Elettronica Università di Roma “La Sapienza”, via Eudossiana 18, I-00184 Roma (2) ENEA Centro Ricerche Fotovoltaiche, Portici I-80085 Napoli, Italy, +39 081 7723220, nobile@portici.enea.it 204KB
15/10/2002 0.00.00 SPATIAL DISTRIBUTION OF EL LIGHT FROM HIGH EFFICIENCY SILICON SOLAR CELLS The angular distribution of infrared radiation emitted by Si-LEDs, realized by direct driving high efficiency single-crystalline silicon solar cells, has been analyzed at different wavelengths in the 1000–1200 nm range and at room temperature. Measurements were carried out at far-field conditions on devices realized with different dimensions and different types of silicon surface texturisation. Planar and inverted-pyramids silicon surface LEDs have shown an integral emission that approaches the cosine function in the 0°–90° interval. For the azimuth angle, a more accurate investigation has been made by selecting wavelength and separating the front from the edge emission. As regards the front emission, planar surface devices show a distribution which deviates from the cosine function at increasing wavelength. Textured surface LEDs, on the contrary, maintain the cosine distribution at the different wavelengths. A sensible edge emission has been revealed, which was investigated in detail by measurements around 90°. The well known correspondence between emission and absorption properties, as dictated by the Kirchhoff law, has been demonstrated valid for our devices as function of emission/absorption angle, by comparing angle-resolved emission and absorption measurements. Keywords: c-Si, High Efficiency, Electroluminescence, Texturisation Pubblicazioni/2002/RomaOC51.pdf A. Parretta1*, L. Ferraioli1, L. Lancellotti1 and M. Tucci1 1ENEA Centro Ricerche Portici, Località Granatello, 80055 Portici (Na), Italy *Corresponding author, Phone: +39 (0)81 7723262; Fax: +39 (0)81 7723344; E-mail: parretta@portici.enea.it P. Maddalena2 and E. Massera2 2INFM, Dipartimento di Scienze Fisiche, Università di Napoli “Federico II”, Via Cintia, I-80126 Napoli, Italy M.A. Green3, A. Wang4 and J. Zhao4 3Centre for Third Generation Photovoltaics, University of New South Wales, Sydney NSW 2052, Australia 4Centre for Photovoltaic Engineering, University of New South Wales, Sydney NSW 2052, Australia 158KB
15/10/2002 0.00.00 ANALYSIS OF LIGHT BACKSCATTERED FROM TEXTURED SILICON SURFACES Light backscattering properties of a variety of textured crystalline silicon samples were analyzed by measuring the aspect ratio of light intensity angular distribution. Unpolarized laser beams at 543 and 633 nm, incident orthogonally to the silicon surface, were used in the experiments. Different types of texturisation were analyzed: inverted pyramids produced by anisotropic etching of single-Si surface, hemispherical wells, produced by isotropic etching of single and multi-Si surface, and porous silicon, produced by electrochemical etching. Measurements of total and diffuse reflectance, performed at the same illumination conditions, were compared with light backscattering measurements. The correlation found between light collection properties of the textured silicon samples with the corresponding aspect ratio and weight of the backdiffused light component is presented and discussed. Keywords: c-Si, Porous Silicon, Texturisation, Light Backscattering Pubblicazioni/2002/RomaOC53.pdf E. Bobeico1, L. Lancellotti1, P. Morvillo1, A. Parretta*1, A. Wang2 and J. Zhao2 1ENEA Centro ricerche Portici, Località Granatello, 80055 Portici (Na), Italy. 2Centre for Photovoltaic Engineering, University of New South Wales, Sydney NSW 2052, Australia. *Corresponding author. Phone: +39 081 7723262; Fax: +39 081 7723344; E-mail: parretta@portici.enea.it 120KB
15/10/2002 0.00.00 MODELLING OF 3D-CPCs FOR CONCENTRATING PHOTOVOLTAIC SYSTEMS The optical modelling of a Compound Parabolic Concentrator (CPC), to be used as photovoltaic solar light concentrator, shows that light distribution on a circular receiver placed at its bottom is far from being uniform, as requested for this type of application. The solution lies in the adding of a prismatic optical mixer, which breaks the circular symmetry of the CPC, distributing light over a square surface. The optimum length of the prism for a uniform distribution of light is twice the base. This is paid by a ~30% reduction of the original CPC concentration ratio. The CPCmixer system has been optimized for medium levels of concentration (~100). The optical efficiency of the CPC-mixer concentrator has been evaluated for different values of the wall reflectance, R, and a total loss of ~6% has been calculated for a 98% reflecting silver coated wall. Pubblicazioni/2002/RomaOE42.pdf A. Parretta*1, P. Morvillo1, C. Privato1, G. Martinelli2 and R. Winston3 1ENEA Centro ricerche Portici, Località Granatello, Portici (Na), I-80055, Italy 2 Dept of Physics,University of Ferrara, Via Paradiso 12, Ferrara (FE), I-44100, Italy 3 Dept. of Physics,University of Chicago, 5640 South Ellis Avenue, Chicago, IL 60637, USA *Corresponding author: Phone: +39 (0)81 7723262; Fax: +39 (0)81 7723344; E-mail: parretta@portici.enea.it 110KB
04/10/2002 0.00.00 HYDROGEN TREATMENT IN a-Si:H/c-Si HETEROJUNCTION FOR PHOTOVOLTAIC APPLICATIONS In this work we investigate the effect of hydrogen RF plasma treatments on crystalline surface of heterojunction based on p-type textured crystalline silicon wafer and n-type film of amorphous silicon deposited by plasma enhanced chemical vapour deposition. To qualify the interfaces we performed capacitance measurements at different temperature in the range of 50 °K up to 300 °K and at different bias conditions using a probe signal frequency in the range 1mHz-1MHz. Finally we measured current voltage characteristics, both in dark and under AM 1.5 condition, to evaluate the recombination mechanism and photovoltaic parameters of devices as solar cells. A good agreement between measured and calculated values by a suitable numerical model was obtained. We conclude that H2 plasma treatment on p-type crystalline silicon surface produces high defect density in the region close to interface. Keywords: Heterojunction, Dry etching, Capacitance measurements, Amorphous silicon, Solar cell. Pubblicazioni/2002/RomaV116.pdf Mario Tucci, Gaetano Contento, Nadia Martucciello, Francesco Roca, Fabrizio Palma* ENEA Research Center, Località Granatello, Portici, 80055 Napoli Italy *Electronic Engineering, University of Rome “La Sapienza”, via Eudossiana 18, I-00184 Roma, Italy, 108KB
04/10/2002 0.00.00 RESEARCH ON Si THIN FILMS IN ENEA BY HOT-WIRE CVD Amorphous and microcrystalline silicon thin films have been prepared by Hot-wire chemical vapor deposition from the decomposition of silane and hydrogen gases in a new multichamber deposition system, designed for the development of thin film solar cells. Graphite resistively heated filaments, which show less degradation than conventional filaments, have been used. Structural and electrical properties of the films have been investigated while scanning the deposition parameter space, and the homogeneity of the deposition process over the substrate area has been tested. Microcrystalline material with strong (220) orientation has been grown at appreciable deposition rate, but the electrical properties still need to be improved to obtain a device quality material. Keywords: Thin film, Micro Crystalline Si, Rapid Growth. Pubblicazioni/2002/RomaV313.pdf Lucia V. Mercaldo*, Paola Delli Veneri, Maria Luisa Addonizio, Carla Minarini, Wu Ruihua†, Carlo Privato ENEA - Portici Research Center Località Granatello, 80055 Portici (NA), Italy 144KB
04/10/2002 0.00.00 PROPERTIES OF LASER CRYSTALLIZED HIGHLY DOPED POLYCRYSTALLINE SILICON FILMS Polycrystalline silicon thin films, 75, 90 and 300 nm thick, have been obtained by Laser Induced Crystallisation at 523 nm wavelength utilizing a Q-switched diode pumped, frequency-doubled Nd:YLF laser. Different n-doped starting amorphous materials have been deposited on glass by LPCVD technique. Irradiation energy density has been varied in order to study its influence on the material. Structural, electrical and optical properties of crystallized films have been investigated. At high energy densities, in a wide range, for the thinner samples, crystallization by laser pulses, partially overlapped, produces material with an homogeneous structure characterized by large crystallite size and high conductivity values. Keywords: Crystallization, Laser Processing, Polycrystalline. Pubblicazioni/2002/RomaV325.pdf P. delli Veneri*, L. V. Mercaldo, C. Minarini, M. A. Nigro, A. Rubino ENEA – Research Center Località Granatello, 80055 Portici (NA), Italy 230KB
04/10/2002 0.00.00 INTEGRATION OF PV AND UPS: ANALYSIS AND TECHNICAL EVALUATION ENEA is working on a new project based on the development of new concept and innovative configurations for photovoltaic systems. The objective is to improve the system performances and to add benefits such as operational quality indices, economy and optimization design size. Two innovative configurations have been selected for study and experimental purpose. The first proposal regards the development of an inverter capable to perform both function of PV grid connected and stand alone concept. The second proposal regards a photovoltaic generator as support and integration of electrical system with conventional UPS. We have tested two types of commercial converters used, both in laboratory and in real operation, for the analysis and correlation among the different indices and variables. The investigation evaluates the technical characteristics and the better design to optimise size, performance and cost. This report presents the results of a preliminary analysis of PV experimental systems installed to the ENEA Portici Research Centre facility. Keywords: Reliability - 1: PV-UPS - 2: Pubblicazioni/2002/RomaV548.pdf G. Graditi (1), F. Apicella, A. Scognamiglio, V. Cataliotti * ENEA R. C. Portici, Loc. Granatello, I-80055 Portici (Na), Italy Tel+39(81)7723111; Fax+39(81)7723344; Email: graditi@ portici.enea.it * Università degli Studi di Palermo, Italy Tel+39(91)6566245; Fax+39(91)488452 (1)Corresponding author: Tel+39(81)7723400; Fax+39(81)7723344; Email: graditi@portici.enea.it 296KB
04/10/2002 0.00.00 Enea’s activities in building integrated grid-connected PV systems ENEA, Italian National Agency for New Technologies, Energy and Environment, is the government research institution involved in the National Photovoltaic Program, which is part of a broader Program about the diffusion of renewable energy in Italy. Within this program the ENEA’s role covers R&D and Demonstration activities as well as technical support to the Government. To promote the diffusion of the photovoltaic technology ENEA has started many activities related to the experimental and demonstrative aspects with particular attention to the Building Integrated Photovoltaic Systems (BIPV) field. Such application is considered very attractive all over the world, because of its main advantages: the electricity generation at or near the point of consumption, the possibility to replace structural elements of the building with a reduction of investment cost. To disseminate technical and economic information and to overcome non-technical barriers, during last years a specific experimental and demonstrative programme was carried out by ENEA: small size grid-connected BIPV systems were designed and realized in many Italian localities. The systems differ for both location in the building and technological characteristics. The first operational data show that the PV systems performance ratio is around 0.70, and the inverter operating efficiency is close to the maximum value declared by the manufactures. In the present paper the three basic ways of integrating PV systems in building: roof, façade, sunshades will be presented and analyzed, by taking into account the solutions adopted on the ENEA’s systems. An accurate analysis of the performance data will allow to compare the different design criteria on the basis of operational and architectural indices. The results so far obtained, in terms of technical and economical information gathered as well as of overcoming of technical and non-technical barriers, have been creating favourable conditions both in the market and in the public opinion. That is confirmed by the success that the National and Regional Roof-Top Programmes are meeting with. Pubblicazioni/2002/RomaV824.pdf G.Graditi (1), T. Contardi, A. Sarno, A. Scognamiglio, F. Apicella ENEA R. C. Portici, Loc. Granatello, I-80055 Portici (Na), Italy Tel+39(81)7723111; Fax+39(81)7723344; Email: graditi@ portici.enea.it (1)Corresponding author: Tel+39(81)7723400; Fax+39(81)7723344; Email: graditi@portici.enea.it 471KB
14/05/2002 0.00.00 THE ITALIAN PV R&D PROGRAMME: STATUS AND PERSPECTIVES Pubblicazioni/2002/NewOrleans.pdf Italy has been active in PV related research for about 30 years. Important results were obtained in a wide range of subjects, and the country gained a leading position of in terms of installed capacity and industrial production until the mid-‘90s. However, the National PV programme did not continue after 1996, which caused an almost immediate drop out of dedicated resources especially in universities, and a general reduced interest for PV. More recently, triggered by the positive situation of the market world-wide, and by environmental concerns which convinced the Government through the Ministry of Environment to launch the “PV roofs“ programme, a more optimistic situation can be seen generally, attracting newcomers, and inducing ENEL and Eni to expand their commitment. There is now an expectation of an Italian R&D programme on photovoltaics encouraged by the Ministries of Research and Industry, which the PV community is looking forward to. 39KB